methacrylic acid-(1-chloro-ethyl ester) | 104218-64-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: methacrylic acid-(1-chloro-ethyl ester)
• 英文别名: Methacrylsaeure-(1-chlor-aethylester)；1-Chlor-1-methacryloyloxy-aethan；1-Chloroethyl 2-methylprop-2-enoate
• CAS: 104218-64-6
• 化学式: C₆H₉ClO₂
• 分子量: 148.589
• InChiKey: JMCVTMBYSNJZGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙醛 、 甲基丙烯酰氯 在 zinc(II) chloride 作用下， 生成 methacrylic acid-(1-chloro-ethyl ester)
  参考文献：
  名称：

  Jakubowitsch et al., Zhurnal Obshchei Khimii, 1958, vol. 28, p. 1930,1934; engl. Ausg. S. 1971, 1974

  摘要：

  DOI：

文献信息

• COMPOSITIONS AND METHODS FOR FORMING ARTICLES HAVING SILVER METAL
  申请人：Eastman Kodak Company

  公开号：US20180362547A1

  公开（公告）日：2018-12-20

  Electrically-conductive silver metal can be provided in a thin film or pattern on a substrate from a silver complex having reducing silver ions and represented by: (Ag + ) a (L) b (P) c (I) wherein L represents an α-oxy carboxylate; P represents a 5- or 6-membered N-heteroaromatic compound; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2. The silver complex is mixed in a hydroxy-free, nitrile-containing aprotic solvent with a polymer that is either (i) a hydroxy-containing cellulosic polymer or (ii) a non-cellulosic acrylic polymer having a halo- or hydroxy-containing side chain. The reducible silver ions in the a thermally sensitive thin film or pattern can be thermally converted to electrically-conductive metallic silver under suitable heating conditions to provide a product article that can be used in various devices.

  电导银金属可由含还原银离子的银配合物以薄膜或图案的形式提供在基底上，其由下式表示： (Ag + ) a (L) b (P) c (I) 其中L代表α-氧基羧酸盐；P代表5或6成员的N-杂环化合物；a为1或2；b为1或2；c为1、2、3或4，条件是当a为1时，b为1，当a为2时，b为2。将银配合物与不含羟基、含腈的无质子溶剂中的聚合物混合，该聚合物为(i)含羟基的纤维素聚合物或(ii)具有卤素或含羟基侧链的非纤维素丙烯酸聚合物。在热敏感薄膜或图案中的可还原银离子可以在适当的加热条件下热转换为电导银金属，以提供可用作各种设备的产品物品。
• Cure Accelerators for Anaerobic Curable Compositions
  申请人：Messana Andrew

  公开号：US20090281335A1

  公开（公告）日：2009-11-12

  The present invention provides compound(s) selected from the group of compounds represented by structural Formula (I): wherein X, Y and R 1 are as described herein, use of such compounds as anaerobic cure accelerators, and compostions including such compounds.

  本发明提供了从由结构式（I）表示的化合物组中选择的化合物，其中X、Y和R1如本文所述，这些化合物作为厌氧固化促进剂的使用，以及包括这些化合物的组合物。
• CURE ACCELERATORS FOR ANAEROBIC CURABLE COMPOSITIONS
  申请人：Henkel IP & Holding GmbH

  公开号：US20170174630A1

  公开（公告）日：2017-06-22

  Cure accelerators for anaerobic curable compositions, such as adhesives and sealants, are provided, and which are defined with reference to the compounds shown in structure I where A is CH 2 or benzyl, R is C 1-10 alkyl, R′ is H or C 1-10 alkyl, or R and R′ taken together may form a four to seven membered ring fused to the benzene ring, R″ is optional, but when R″ is present, R″ is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl, and EWG is as shown, an electron withdrawing group, such as nitro, nitrile, carboxylate or trihaloalkyl.

  为氧化还原固化组合物（如胶粘剂和密封剂）提供了用于加速固化的固化催化剂，其定义参考结构I中显示的化合物，其中A为CH2或苄基，R为C1-10烷基，R′为H或C1-10烷基，或者R和R′一起可以形成与苯环融合的四至七元环，R″是可选的，但当R″存在时，R″是卤素、烷基、烯基、环烷基、羟基烷基、羟基烯基、烷氧基、氨基、烷基-或烯基-醚、烷基（甲基）丙烯酸酯、羰基、羧基、亚硝基、磺酸酯、羟基或卤代烷基，以及EWG如所示，是一种电子吸引基团，如硝基、腈基、羧酸盐或三卤代烷基。
• [EN] (METH)ACRYLATE-FUNCTIONALIZED WAXES AND CURABLE COMPOSITIONS MADE THEREWITH<br/>[FR] CIRES FONCTIONNALISÉES PAR (MÉTH)ACRYLATE ET COMPOSITIONS DURCISSABLES FABRIQUÉES AVEC CELLES-CI
  申请人：HENKEL IP & HOLDING GMBH

  公开号：WO2020119908A1

  公开（公告）日：2020-06-18

  The present invention relates to (meth)acrylate-functionalized waxes and curable compositions, such as anaerobic adhesive compositions, made therewith.

  本发明涉及（甲基）丙烯酸酯官能化蜡和由此制成的可固化组合物，例如厌氧胶黏剂组合物。
• Multi-functional alpha-alkoxyalkyl acrylate and methacrylate ester compositions and reworkable polymers formed therefrom
  申请人：Woods G. John

  公开号：US20050101689A1

  公开（公告）日：2005-05-12

  Adhesive compositions are disclosed which include acrylates, their polymers, and free radical initiators. The compositions include a multi-functional alpha-alkoxyalkyl(meth)acrylate compound and a free radical initiator. The multi-functional alpha-alkoxyalkyl(meth)acrylate compound is the reaction product of: (a) a (meth)acrylic acid or a (meth)acrylate ester having a free carboxylic acid group; and (b) a compound including two or more 1-alkenyl ether groups and free of acetal and ketal groups, or a compound free of acetal and ketal groups and including one or more 1-alkenyl ether groups and a (meth)acrylate group. The compositions are easier and less expensive to prepare than conventional acrylate compositions and degrade when contacted with an acid medium or when heated. The compositions are useful in a wide range of applications and are compatible with conventional adhesive additives.

  本发明揭示了包括丙烯酸酯、它们的聚合物和自由基引发剂的粘合剂组合物。该组合物包括多功能α-烷氧基烷基（甲基）丙烯酸酯化合物和自由基引发剂。多功能α-烷氧基烷基（甲基）丙烯酸酯化合物是以下反应产物：（a）自由羧酸基的（甲基）丙烯酸或（甲基）丙烯酸酯；和（b）包括两个或更多1-烯基醚基团且不含缩醛和缩酮基团的化合物，或不含缩醛和缩酮基团且包括一个或多个1-烯基醚基团和（甲基）丙烯酸酯基团的化合物。该组合物比传统的丙烯酸酯组合物更易于制备，成本更低，并在接触酸性介质或加热时降解。该组合物在广泛的应用中非常有用，并且与传统的粘合剂添加剂兼容。