N,N-二丁基-1H-苯并三唑-1-甲胺 | 15497-45-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 中文名称: N,N-二丁基-1H-苯并三唑-1-甲胺
• 英文名称: N,N-dibutyl-1H-benzotriazole-1-methylamine
• 英文别名: N-(benzotriazol-1-ylmethyl)-N-butylbutan-1-amine
• CAS: 15497-45-7
• 化学式: C₁₅H₂₄N₄
• 分子量: 260.382
• InChiKey: CODGFEFCDWSFSV-UHFFFAOYSA-N

物化性质

• 沸点：
  383.5±25.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  N,N-二丁基-1H-苯并三唑-1-甲胺 、 3-溴丙烯 在 bismuth(III) chloride 、 氢化铝 作用下， 以 四氢呋喃 、 水 为溶剂， 以83%的产率得到but-3-enyldibutylamine
  参考文献：
  名称：

  Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

  摘要：

  In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.

  DOI：

  10.1016/s0040-4039(00)92139-7
• 作为产物：
  描述：

  1H-苯并三唑-1-甲醇 、 二正丁胺 生成 N,N-二丁基-1H-苯并三唑-1-甲胺
  参考文献：
  名称：

  Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

  摘要：

  In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.

  DOI：

  10.1016/s0040-4039(00)92139-7

文献信息

• A General Synthesis of 1-(Dialkylaminomethyl)indoles
  作者：Brian E. Love、Binh T. Nguyen

  DOI：10.1055/s-1998-1883

  日期：1998.10

  1-(N,N-Dialkylamino)methylindoles are prepared from the corresponding 1-(dialkylaminomethyl)benzotriazoles by treatment with indole and base. The aminoalkylation proceeds in high yield with good regioselectivity.

  1-(N,N-二烷基氨基)甲基吲哚是通过用吲哚和碱处理相应的1-(二烷基氨基甲基)苯并三唑制备的。氨基烷基化反应在高产率和良好区域选择性的条件下进行。
• REFRIGERANT OIL FOR FREEZERS AND OPERATING FLUID COMPOSITION FOR FREEZERS
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2471896A1

  公开（公告）日：2012-07-04

  The working fluid composition for a refrigerating machine of this invention comprises a base oil containing an ether-based compound, an amine salt of an acidic phosphoric acid ester, at least one compound selected from the group consisting of amine-based antioxidants, metal inactivating agents and alicyclic epoxy compounds, and an unsaturated fluorinated hydrocarbon refrigerant. The refrigerating machine oil of the invention comprises a base oil containing an ether-based compound, an amine salt of an acidic phosphoric acid ester, and at least one compound selected from the group consisting of amine-based antioxidants, metal inactivating agents and alicyclic epoxy compounds, and it is to be used together with an unsaturated fluorinated hydrocarbon refrigerant.

  本发明的制冷机工作液组合物包括一种基础油，其中含有一种醚基化合物、一种酸性磷酸酯的胺盐、至少一种选自由胺类抗氧化剂、金属失活剂和脂环族环氧化合物组成的组中的化合物，以及一种不饱和含氟碳氢化合物制冷剂。本发明的冷冻机油包括一种基础油，其中含有一种醚基化合物、一种酸性磷酸酯的胺盐和至少一种从胺基抗氧化剂、金属失活剂和脂环族环氧化合物组成的组中选出的化合物，它将与一种不饱和含氟烃类制冷剂一起使用。
• Refrigerant oil for freezers and operating fluid composition for freezers
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2733192A1

  公开（公告）日：2014-05-21

  The present invention relates to a working fluid composition for a refrigerating machine comprising a refrigerating machine oil comprising a base oil containing an ether-based compound, an amine salt of an acidic phosphoric acid ester and at least one further compound selected from the group consisting of amine-based antioxidants, metal inactivating agents and alicyclic epoxy compounds, and an unsaturated fluorinated hydrocarbon refrigerant, wherein the content of the amine salt of the acidic phosphoric acid ester is not greater than 1000 ppm by mass based on the total amount of the refrigerating machine oil. It further relates to the use of a composition as a refrigerating machine oil.

  本发明涉及一种用于制冷机的工作流体组合物，该组合物包括一种制冷机油，该制冷机油由含有醚基化合物的基础油、酸性磷酸酯的胺盐和至少一种选自胺基抗氧化剂、金属失活剂和脂环族环氧化合物以及不饱和含氟烃类制冷剂的组中的其他化合物组成、其中酸性磷酸酯胺盐的含量以冷冻机油总量为基准，不超过 1000 ppm（质量分数）。它还涉及一种组合物作为冷冻机油的用途。
• HARTMANN, KLAUS;EITNER, BERND;BUCHNER, RAINER;BRENDEL, HELGA;RAUHUT, HEID+
  作者：HARTMANN, KLAUS、EITNER, BERND、BUCHNER, RAINER、BRENDEL, HELGA、RAUHUT, HEID+

  DOI：——

  日期：——
• Lubricants That Decrease Micropitting for Industrial Gears
  申请人：Ward William C.

  公开号：US20090093384A1

  公开（公告）日：2009-04-09

  The invention relates to an industrial gear formulation containing a high TBN overbased detergent that results in decreasing micropitting for industrial gears.