di(3,5,5-trimethylhexyl) 1,2-cyclohexanedicarboxylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: di(3,5,5-trimethylhexyl) 1,2-cyclohexanedicarboxylate
• 英文别名: Bis(3,5,5-trimethylhexyl) cyclohexane-1,2-dicarboxylate
• 化学式: C₂₆H₄₈O₄
• 分子量: 424.665
• InChiKey: YELNFXQNZUASEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  30
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,5,5-三甲基-1-己醇 、 六氢苯酐 在 tin oxide 作用下， 以 xylene 为溶剂， 225.0~230.0 ℃ 、20.0 kPa 条件下， 反应 8.0h， 生成 di(3,5,5-trimethylhexyl) 1,2-cyclohexanedicarboxylate
  参考文献：
  名称：

  Dicarboxylic diester, process for producing the same, and refrigerating machine lubricating oil comprising the ester

  摘要：

  由以下公式表示的二酯，其中A代表环己烷环、环己烯环或苯环，X为H或甲基基团，RX和RY相同或不同，且每个均为C3-C18支链烷基基团、C1-C18直链烷基基团、C2-C18直链烯基或C3-C18环烷基，前提是当A为苯环时，RX和RY彼此不同，且—COORX和—COORY连接到苯环的两个相邻碳原子，并具有以下特性：1）总酸值为0.05 mgKOH/g或更低，2）硫酸盐灰分含量为10 ppm或更低，3）硫含量为20 ppm或更低，4）磷含量为20 ppm或更低，5）过氧化值为1.0 meq/kg或更低，6）羰基值为10或更低；7）体积电阻率为1×1011Ω·cm或更高，8）羟值为3 mgKOH/g或更低，9）水含量为100 ppm或更低，制备该二酯的方法以及包含该二酯的制冷剂润滑油。

  公开号：

  US20050038283A1

文献信息

• Refrigerator oil composition, and method of using the composition for lubrication
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP1008643A2

  公开（公告）日：2000-06-14

  Provided is a refrigerator oil composition comprising a refrigerant that comprises carbon dioxide (CO2) as the essential component, and an ester-based lubricating oil composition; wherein the ratio of refrigerant/lubricating oil composition falls between 99/1 and 10/90 by weight. The refrigerator oil composition has good lubricity and sealability and can be stably used for a long period of time in a compression refrigeration cycle in which is used a refrigerant comprising CO2 as the essential component. Also provided is a method of using the composition for lubricating a compression refrigeration cycle equipped with an oil separator and/or a hot gas line.

  本发明提供了一种冷冻机油组合物，它包括一种以二氧化碳（CO2）为基本成分的制冷剂和一种酯基润滑油组合物；其中制冷剂/润滑油组合物的重量比介于 99/1 和 10/90 之间。该冷冻机油组合物具有良好的润滑性和密封性，可在以二氧化碳为主要成分的制冷剂的压缩制冷循环中长期稳定使用。此外，还提供了一种使用该组合物的方法，用于润滑装有油分离器和/或热气管路的压缩制冷循环。
• REFRIGERATING MACHINE OIL COMPOSITION FOR CARBON DIOXIDE REFRIGERANT
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1203807A1

  公开（公告）日：2002-05-08

  The invention relates to a refrigerator oil composition for compression refrigerators with carbon dioxide refrigerant therein, such as car air conditioners, refrigerators, freezers, air conditioners, heat pumps, etc. The base oil of the composition comprises an oxygen-containing organic compound as the essential component and has a kinematic viscosity at 100°C of from 5 to 50 mm2/sec, a viscosity index of at least 60, and a water content of at most 300 ppm.

  本发明涉及一种冷冻机油组合物，用于装有二氧化碳制冷剂的压缩式冷冻机，如汽车空调、冰箱、冰柜、空调、热泵等。该组合物的基础油以含氧有机化合物为主要成分，100°C 时的运动粘度为 5 至 50 mm2/sec，粘度指数至少为 60，含水量不超过 300 ppm。
• LUBRICATING OIL FOR REFRIGERATOR, HYDRAULIC FLUID COMPOSITION FOR REFRIGERATOR AND METHOD FOR LUBRICATION OF REFRIGERATOR
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1225213A1

  公开（公告）日：2002-07-24

  The invention provides a lubricating oil for refrigerators, comprising (a) at least one ester represented by the formula (1) wherein R1 is C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; R2 is H, C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; with the poviso that the total number of carbons contained in the alkyls represented by R1 and R2 is 2 to 18 and that when R2 is H, R1 is branched-chain alkyl; and R3 is C1 to C20 straight-chain alkyl, C3 to C20 branched-chain alkyl or C3 to C10 cycloalkyl, optionally in combination with (b) at least one member selected from the group consisting of fatty acid polyol esters, phthalic acid esters, alicyclic dicarboxylic acid esters, polyvinyl ethers, hydrocarbon oils and polyalkylene glycols; as well as a method for lubricating a refrigerator using such a lubricating oil, and a working fluid composition for refrigerators comprising (I) component (a) or components (a) and (b) and (II) a refrigerant.

  本发明提供了一种用于冰箱的润滑油，包括 (a) 至少一种由式 (1) 代表的酯类 其中 R1 是 C1 至 C18 直链烷基或 C3 至 C18 支链烷基；R2 是 H、C1 至 C18 直链烷基或 C3 至 C18 支链烷基；前提是 R1 和 R2 所代表的烷基所含的碳总数为 2 至 18，且当 R2 为 H 时，R1 为支链烷基；和 R3 是 C1 至 C20 直链烷基、C3 至 C20 支链烷基或 C3 至 C10 环烷基，可选择与 (b) 至少一种选自脂肪酸多元醇酯、邻苯二甲酸酯、脂环二羧酸酯、聚乙烯醚、烃油和聚烷基二 醇组成的组的成员结合使用；以及一种使用这种润滑油润滑冰箱的方法，和一种用于冰箱的工作液组合物，该组合物包括 (I) 成分 (a) 或成分 (a) 和 (b) 以及 (II) 制冷剂。
• DICARBOXYLIC DIESTER, PROCESS FOR PRODUCING THE SAME, AND REFRIGERATING MACHINE LUBRICATING OIL COMPRISING THE ESTER
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1227078A1

  公开（公告）日：2002-07-31

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, RX and RY are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C10 cycloalkyl, provided that when A is a benzene ring, RX and RY are different from each other and -COORX and -COORY are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1 x 1011 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由式表示的二酯 其中 A 代表环己烷环、环己烯环或苯环，X 为 H 或甲基，RX 和 RY 相同或不同，且各自为 C3-C18 支链烷基、C1-C18 直链烷基、C2-C18 直链烯基或 C3-C10 环烷基，条件是当 A 为苯环时，RX 和 RY 彼此不同，且 -COORX 和 -COORY 连接到苯环的两个相邻碳原子上，并具有以下性质： 1) 总酸数不超过 0.05 mgKOH/g、 2) 硫酸盐灰分含量不超过 10 ppm、 3) 硫含量不超过 20 ppm、 4) 磷含量不超过 20 ppm、 5) 过氧化值等于或小于 1.0 meq/kg、 6) 羰基值等于或小于 10； 7) 体积电阻率等于或大于 1 x 1011 Ω-cm、 8) 羟值为 3 mgKOH/g 或更低，以及 9) 含水量等于或小于 100 ppm、 制备该二元酯的工艺和包含该二元酯的冷冻机润滑油。
• LUBRICATING OIL COMPOSITION CONTAINING CYCLIC ORGANOPHOSPHORUS COMPOUND
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1243641A1

  公开（公告）日：2002-09-25

  A lubricating oil composition which comprises at least one compound selected from specific cyclic organic phosphorus compounds is disclosed. The lubricating oil composition exhibits excellent extreme pressure property, seizure resistance and wear resistance and is advantageously used as bearing oil, gear oil, hydraulic oil and refrigerator oil.

  本发明公开了一种润滑油组合物，其中包含至少一种选自特定环状有机磷化合物的化合物。 该润滑油组合物具有优异的极压特性、抗咬合性和耐磨性，可用作轴承油、齿轮油、液压油和冷冻机油。