2,11,20,29,37,38,39,40-Octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13(18),14,16,19(39),20,22(27),23,25,28(38),30,32,34-nonadecaene-6,15,24,33-tetrasulfonyl chloride | 75922-27-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,11,20,29,37,38,39,40-Octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13(18),14,16,19(39),20,22(27),23,25,28(38),30,32,34-nonadecaene-6,15,24,33-tetrasulfonyl chloride
• 英文别名: 2,11,20,29,37,38,39,40-octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13(18),14,16,19(39),20,22(27),23,25,28(38),30,32,34-nonadecaene-6,15,24,33-tetrasulfonyl chloride
• CAS: 75922-27-9
• 化学式: C₃₂H₁₄Cl₄N₈O₈S₄
• 分子量: 908.588
• InChiKey: LSIAVDNRKZPPIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  56
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  279
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  2,11,20,29,37,38,39,40-Octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13(18),14,16,19(39),20,22(27),23,25,28(38),30,32,34-nonadecaene-6,15,24,33-tetrasulfonyl chloride 、 N-(rhodamine-6G)lactam-ethylenediamine 在 三乙胺 作用下， 以 氯仿 、 丙酮 为溶剂， 反应 2.0h， 以14%的产率得到
  参考文献：
  名称：

  Phthalocyanines and related compounds: XLIV. Synthesis of conjugates of phthalocyanines with rhodamines

  摘要：

  A series of conjugates of sulfo- and carboxy-substituted phthalocyanines with rhodamines were prepared, and their electronic absorption and luminescence spectra were studied. An intramolecular transfer of the excitation energy from the rhodamine moiety (donor) to the phthalocyanine moiety (acceptor) was revealed.

  DOI：

  10.1134/s1070363207060291
• 作为产物：
  描述：

  sodium phthalocyanine tetrasulfonate 在 氯化亚砜 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 生成 2,11,20,29,37,38,39,40-Octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13(18),14,16,19(39),20,22(27),23,25,28(38),30,32,34-nonadecaene-6,15,24,33-tetrasulfonyl chloride
  参考文献：
  名称：

  Phthalocyanines and related compounds: XLIV. Synthesis of conjugates of phthalocyanines with rhodamines

  摘要：

  A series of conjugates of sulfo- and carboxy-substituted phthalocyanines with rhodamines were prepared, and their electronic absorption and luminescence spectra were studied. An intramolecular transfer of the excitation energy from the rhodamine moiety (donor) to the phthalocyanine moiety (acceptor) was revealed.

  DOI：

  10.1134/s1070363207060291

文献信息

• Phthalocyanines and related compounds: XLIV. Synthesis of conjugates of phthalocyanines with rhodamines
  作者：V. M. Derkacheva、S. A. Mikhalenko、L. I. Solov’eva、V. I. Alekseeva、L. E. Marinina、L. P. Savina、A. V. Butenin、E. A. Luk’yanets

  DOI：10.1134/s1070363207060291

  日期：2007.6

  A series of conjugates of sulfo- and carboxy-substituted phthalocyanines with rhodamines were prepared, and their electronic absorption and luminescence spectra were studied. An intramolecular transfer of the excitation energy from the rhodamine moiety (donor) to the phthalocyanine moiety (acceptor) was revealed.