1-(2-furyl)ethyl bis[2-(2-furyl)ethyl]diselenophosphinate | 1351415-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 1-(2-furyl)ethyl bis[2-(2-furyl)ethyl]diselenophosphinate
• 英文别名: Bis[2-(furan-2-yl)ethyl]-[1-(furan-2-yl)ethylselanyl]-selenidophosphanium；bis[2-(furan-2-yl)ethyl]-[1-(furan-2-yl)ethylselanyl]-selenidophosphanium
• CAS: 1351415-45-6
• 化学式: C₁₈H₂₁O₃PSe₂
• 分子量: 474.257
• InChiKey: XEDYGBCBYCWAHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.73
• 重原子数：
  24
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  39.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-乙烯基呋喃 在 磷化氢 、 selenium 、 水 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 二甲基亚砜 、 甲苯 为溶剂， 反应 3.0h， 生成 1-(2-furyl)ethyl bis[2-(2-furyl)ethyl]diselenophosphinate
  参考文献：
  名称：

  A three-component reaction between alkenes, secondary phosphanes, and elemental selenium: a novel, efficient, atom-economic synthesis of diselenophosphinic esters

  摘要：

  A novel, convenient, atom-economic approach toward the synthesis of diselenophosphinic esters has been developed via the three-component reaction between aryl- or hetarylalkenes secondary phosphanes, and elemental selenium. The reaction proceeds without a catalyst (85 degrees C, 3 h, 1,4-dioxane) to afford the target compounds in good to high yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.10.094

文献信息

• A three-component reaction between alkenes, secondary phosphanes, and elemental selenium: a novel, efficient, atom-economic synthesis of diselenophosphinic esters
  作者：Nina K. Gusarova、Alexander V. Artem’ev、Svetlana F. Malysheva、Ol’ga A. Tarasova、Boris A. Trofimov

  DOI：10.1016/j.tetlet.2011.10.094

  日期：2011.12

  A novel, convenient, atom-economic approach toward the synthesis of diselenophosphinic esters has been developed via the three-component reaction between aryl- or hetarylalkenes secondary phosphanes, and elemental selenium. The reaction proceeds without a catalyst (85 degrees C, 3 h, 1,4-dioxane) to afford the target compounds in good to high yields. (C) 2011 Elsevier Ltd. All rights reserved.