3-(4-Phenyl-thiosemicarbazono)-buttersaeureaethylester | 40206-87-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-(4-Phenyl-thiosemicarbazono)-buttersaeureaethylester
• 英文别名: ethyl 3-(phenylcarbamothioylhydrazinylidene)butanoate
• CAS: 40206-87-9
• 化学式: C₁₃H₁₇N₃O₂S
• 分子量: 279.363
• InChiKey: KYVDRLORSUNLMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  94.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-(4-Phenyl-thiosemicarbazono)-buttersaeureaethylester 在 sodium acetate 、 一水合肼 作用下， 以 乙醇 为溶剂， 反应 9.0h， 生成 1-Phenylamino-4-phenylazo-5-methylpyrazolo<3,2-c>triazole
  参考文献：
  名称：

  Mohareb, Rafat M.; Shams, Hoda Z.; Elkholy, Yehia M., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 72, # 1-4, p. 93 - 102

  摘要：

  DOI：

文献信息

• SYNTHESIS, CHARACTERISATION, CATALYTIC, AND BIOCIDAL STUDIES OF RUTHENIUM(III) COMPLEXES WITH THIOSEMICARBAZONES OF β-DIKETOESTERS
  作者：C. Jayabalakrishnan、R. Karvembu、K. Natarajan

  DOI：10.1081/sim-120013023

  日期：2002.11.7

  Ruthenium(III) complexes, [RuX(EPh3)(2)(L)] (X=Cl, Br; E=P, As; L=tridentate Schiff base dianion), have been synthesised by reacting [RuCl3(PPh3)(3)], [RuCl3(AsPh3)(3)] or [RuBr3(AsPh3)(3)] with thiosemicarbazones of methyl- and ethyl acetoacetates. All of the new complexes have been characterised by elemental analyses, IR, electronic, EPR and cyclic voltammetric data and an octahedral structure has been tentatively proposed. The ruthenium(III) complexes were found to be effective catalysts for the oxidation of alcohols to the corresponding carbonyl compounds in the presence of N-methylmorpholine-N-oxide (NMO) as a co-oxidant. The Schiff bases and the new complexes have been tested for the in vitro growth inhibitory activity against the bacteria E. Coli, Bacillus sp. and Pseudomonas sp.
• Mohareb, Rafat M.; Shams, Hoda Z.; Elkholy, Yehia M., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 72, # 1-4, p. 93 - 102
  作者：Mohareb, Rafat M.、Shams, Hoda Z.、Elkholy, Yehia M.

  DOI：——

  日期：——