Convenient One-Pot Synthesis of β-Alkylthio Acid Derivatives from Thioacetates and the Corresponding α,β-Unsaturated Compounds
作者:Dong Won Lee、Jaesung Choi、Nung Min Yoon
DOI:10.1080/00397919608003578
日期:1996.6
Various β-alkylthio acid derivatives were prepared conveniently from thioacetates and α,β-unsaturated compounds through borohydride exchange resin (BER)-Pd catalyzed transesterification of thioacetates to the corresponding thiols and Michael addition of the resulting thiols to α,β-unsaturated compounds.
摘要 通过硼氢化物交换树脂 (BER)-Pd 催化硫代乙酸酯与相应硫醇的酯交换反应以及所得硫醇与 α,β-不饱和化合物的迈克尔加成,可以方便地从硫代乙酸酯和 α,β-不饱和化合物制备各种 β-烷基硫代酸衍生物。 .