1H-imidazol-3-ium benzoate | 18715-52-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1H-imidazol-3-ium benzoate
• 英文别名: imidazole*benzoic acid；imidazolium benzoate；1H-imidazole; benzoate；1H-Imidazol; Benzoat；1H-imidazol-3-ium;benzoate
• CAS: 18715-52-1
• 化学式: C₃H₄N₂*C₇H₆O₂
• 分子量: 190.202
• InChiKey: GHTDJAAAAJNCLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.79
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯甲酰氯 在 苯 作用下， 生成 1H-imidazol-3-ium benzoate
  参考文献：
  名称：

  Gerngross, Chemische Berichte, 1913, vol. 46, p. 1913

  摘要：

  DOI：

文献信息

• IMIDAZOLIUM MONOCARBOXYLATE SALT AND METHOD FOR PREPARATION THEREOF
  申请人：RAJENDRAN GOVINDASAMY PARAMASIVAM

  公开号：US20120157688A1

  公开（公告）日：2012-06-21

  Imidazolium monocarboxylate salt compositions are suitable for use as latent catalysts in curable epoxy compositions. The curable compositions prepared therefrom are used to prepare coated substrates, and to produce conformally sealed printed wiring boards. Method for preparation and curing are also provided. Of particular utility are compositions comprising 2-ethyl-4-methyl imidazolium monocarboxylate salts.

  咪唑单羧酸盐组合物适用于作为固化环氧组合物中的潜在催化剂。由此制备的固化组合物用于制备涂覆基材，并生产符合密封标准的印刷线路板。还提供了制备和固化的方法。特别实用的是含有2-乙基-4-甲基咪唑单羧酸盐的组合物。
• Toward a new type of proton conductor based on imidazole and aromatic acids
  作者：Sylwia Zięba、Alina T. Dubis、Andrzej K. Gzella、Paweł Ławniczak、Katarzyna Pogorzelec-Glaser、Andrzej Łapiński

  DOI：10.1039/c9cp01888c

  日期：——

  imidazole, one with benzoic acid having one carboxylic acid group and another with salicylic acid having a carboxylic and hydroxyl group located in the ortho position, were synthesized. Physical properties of these newly synthesized proton conducting salts were investigated using experimental and theoretical methods. The structures of these salts were studied by X-ray diffraction and 1H and 13C NMR techniques

  提出了一种新的方法来获得基于芳族酸和杂环碱的质子传导材料。这可能会导致一种新材料，其中所有氢键键合强度均为中等或弱，并且碱和酸分子可能会旋转。如果满足上述条件，则可以预期到由格罗特斯机制控制的高质子传导率值。合成了两种咪唑的盐，一种是与具有一个羧酸基的苯甲酸，另一种是与具有在邻位的羧基和羟基的水杨酸的盐。使用实验和理论方法研究了这些新合成的质子传导盐的物理性质。这些盐的结构通过X射线衍射和11 H和13 C NMR技术。在QTAiM理论内，通过DFT计算，并通过Hirshfeld表面分析，分析了盐中的分子间相互作用。还讨论了π-π相互作用，质子传导途径和传输机理。
• An imidazole-based organocatalyst designed for bulk polymerization of lactide isomers: inspiration from Nature
  作者：Olivier Coulembier、Thomas Josse、Brieuc Guillerm、Pascal Gerbaux、Philippe Dubois

  DOI：10.1039/c2cc37061a

  日期：——

  The design of an imidazole-based salt by enzyme-mimicking allowed controlling the ring-opening polymerization of L- and D-LA monomers in bulk. Kinetic study supports a bifunctional activation process only slightly different from the one occurring in Nature.

  通过酶模拟的咪唑基盐的设计允许控制大量的L-和D-LA单体的开环聚合。动力学研究支持双功能激活过程，与自然界中的激活过程仅稍有不同。
• Reaction of Imidazole and 2-Methylimidazole with Copper(II) Salts and Certain Acids
  作者：N. A. Skorik、K. A. Il’ina、V. V. Kozik

  DOI：10.1134/s0036023621110188

  日期：2021.11

  prepared poorly soluble copper(II) benzoate Cu(C7H5O2)2 · 3H2O and nicotinate Cu(C6H4NO2)2 · H2O with imidazole and 2-methylimidazole has been determined. Mono- and biligand salts have been analyzed and their thermal decomposition has been studied. IR spectroscopy has shown the participation of pyridine nitrogen of imidazole and carboxylic groups of aromatic acids in binding to copper(II) ion. Composition

  摘要 双配体化合物的组成 Cu(C 3 H 4 N 2 , C 4 H 6 N 2 ) x ( \(\textC}}}}_\text7}}}}\text H}}}_\text5}}}}\textO}}_2}^ - },\) \(\textC}}}}_\ text6}}}}\textH}}}_\text4}}}}\textNO}}_2}^ - }\) ) 2 · n H 2通过制备的难溶铜的水性悬浮液的反应而得到的O（II）苯甲酸甲酯的Cu（C 7 H ^ 5 ö 2）2  ·3H 2 O和烟的Cu（C 6 H ^ 4 NO 2) 2 · H 2 O 与咪唑和 2-甲基咪唑已被测定。已经分析了单配体盐和双配体盐并研究了它们的热分解。红外光谱显示咪唑的吡啶氮和芳香酸的羧基参与与铜 (II) 离子的结合。苯甲酸铜(II) 络合物的组成和稳定性，盐Cu(C
• MANUFACTURING OF SKIN-COMPATIBLE ELECTRODES
  申请人：Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO

  公开号：EP3705035A1

  公开（公告）日：2020-09-09

  A method of manufacturing a skin-compatible electrode (100) comprises printing a circuit pattern (P1) onto a flexible substrate (200) to form an electrically conductive pattern including an electrode pad area (301). A layer of an adhesive composition (401p) is printed in a second pattern (P2) onto the electrode pad area (301) to form an adhesive interface layer (401). The adhesive interface layer (401) is a dry film formed from the adhesive composition (401p) comprising an ionically conductive pressure sensitive adhesive composition comprising a resin (R), an ionic liquid (I), and optionally electrically conductive particles (P). A layer thickness and material of the flexible substrate, the conductive pattern, and the conductive adhesive interface have relatively low stiffness in plane of the flexible substrate (200).

  一种制造皮肤兼容电极（100）的方法包括在柔性基板（200）上印刷电路图案（P1），以形成包括电极垫区域（301）的导电图案。在电极垫区域（301）上以第二图案（P2）印刷一层粘合剂组合物（401p），以形成粘合剂界面层（401）。粘合剂界面层（401）是由粘合剂组合物（401p）形成的干膜，粘合剂组合物包括由树脂（R）、离子液体（I）和可选导电颗粒（P）组成的离子导电压敏粘合剂组合物。柔性基板、导电图案和导电粘合剂界面的层厚度和材料在柔性基板（200）平面上具有相对较低的刚度。