3-Methyl-3-phenoxymethyl-oxetan | 3894-19-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-Methyl-3-phenoxymethyl-oxetan
• 英文别名: Oxetane, 3-methyl-3-phenoxymethyl；3-methyl-3-(phenoxymethyl)oxetane
• CAS: 3894-19-7
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: DMVWICDWJIUWPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Methyl-3-phenoxymethyl-oxetan 在 lithium aluminium tetrahydride 作用下， 生成 2,2-dimethyl-3-phenoxy-1-propanol
  参考文献：
  名称：

  Seyden-Penne,J. et al., Bulletin de la Societe Chimique de France, 1965, p. 700 - 704

  摘要：

  DOI：

文献信息

• Efficient Synthesis of γ‐Lactones by Cobalt‐Catalyzed Carbonylative Ring Expansion of Oxetanes under Syngas Atmosphere
  作者：Yitian Tang、Chaoren Shen、Qiyi Yao、Xinxin Tian、Bo Wang、Kaiwu Dong

  DOI：10.1002/cctc.202001294

  日期：2020.12.4

  A practical route from oxetane or thietane to γ‐(thio)butyrolactone via solvated‐proton‐assisted cobalt‐catalyzed carbonylative ring expansion under syngas atmosphere has been established. A wide variety of γ‐(thio)butyrolactones can be afforded in good to excellent yields. The versatility of this method has been well demonstrated in the synthesis of intermediates towards the natural product Arctigenin

  建立了在合成气气氛下通过溶剂化的质子辅助的钴催化的羰基化环膨胀从氧杂环丁烷或硫杂环丁烷生成γ-（硫代）丁内酯的实用路线。可以提供种类繁多的γ-（硫代）丁内酯，收率非常好。该方法的多功能性已在针对天然产物牛黄菌素以及药物巴氯芬和孟鲁司特的中间体的合成中得到了充分证明。已合理解释了观察到的乙二醇醚溶剂的促进作用。
• Reactive diluent and curable resin composition
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：US20030199655A1

  公开（公告）日：2003-10-23

  The present invention provides a reactive diluent composition which overcomes drawbacks of both the radical-cure and the cationic-cure reactive diluents and can be applied in a broad variety of uses such as paints, inks, adhesives, pressure sensitive adhesives, surface-modifiers, and molding materials; a curable resin composition containing the same; an activated energy ray-curable resin composition; and an activated energy ray-curable ink composition for ink-jet printing. A reactive diluent composition comprising a vinyl ether group-containing (meth)acrylic ester represented by the following general formula (1): CH 2 ═CR 1 —COO—R 2 —O—CH═CH—R 3 (1) wherein R 1 represents a hydrogen atom or a methyl group; R 2 represents an organic residue of 2 to 20 carbon atoms; R 3 represents a hydrogen atom or an organic residue of 1 to 11 carbon atoms and a hydroxyl group-containing polymerizable compound and/or divinyl ether.

  本发明提供了一种反应性稀释剂组合物，克服了自由基固化和阳离子固化反应性稀释剂的缺点，并可广泛应用于涂料、油墨、粘合剂、压敏粘合剂、表面改性剂和模塑材料等各种用途；一种可固化树脂组合物，其中包含该反应性稀释剂组合物；一种活性能量射线可固化的树脂组合物；以及适用于喷墨打印的活性能量射线可固化的油墨组合物。所述反应性稀释剂组合物包括以下通式（1）所表示的含乙烯基醚基的（甲）丙烯酸酯：CH2═CR1—COO—R2—O—CH═CH—R3(1)，其中R1表示氢原子或甲基基团；R2表示2至20个碳原子的有机残基；R3表示氢原子或1至11个碳原子的有机残基和一个含羟基的可聚合化合物和/或二乙烯醚。
• ELECTROLYTE MATERIAL, AND BATTERY MATERIAL AND SECONDARY BATTERY USING SAID ELECTROLYTE MATERIAL
  申请人：Hashimoto Masashi

  公开号：US20120244427A1

  公开（公告）日：2012-09-27

  The present invention provides a stable electrolyte material that provides high safety, exhibits favorable ionic conductivity not only at room temperature but also in the low temperature range at or below room temperature, has excellent reduction resistance, and can be suitably used as a material of a lithium ion cell. The electrolyte material includes, as essential components, a specific polymer having an ether bond in a side chain thereof, and a specific electrolyte salt.

  本发明提供了一种稳定的电解质材料，具有高安全性，在室温下和低于室温的低温范围内表现出良好的离子导电性，具有优异的还原电阻，可适当用作锂离子电池的材料。电解质材料包括具有侧链中的醚键的特定聚合物和特定电解质盐作为必要组分。
• IMAGE FORMING METHOD
  申请人：GOTOU Hiroshi

  公开号：US20130155145A1

  公开（公告）日：2013-06-20

  An image forming method applying a pretreatment liquid on the surface of a recording medium; and applying an inkjet ink including a colorant, a hydrosoluble organic solvent, a surfactant and water on the surface applied with the pretreatment liquid, wherein the hydrosoluble organic solvent includes at least one polyol including an equilibrium water content in an amount not less than 30% by weight at 23° C. and 80% RH; an amide compound having the following formula (I); and at least one of compounds having the following formulae (II) to (IV), and wherein a pure water transfers to the recording medium in an amount of from 1 to 15 mL/m 2 when measured by a dynamic scanning liquid absorptometer at a contact time of 100 ms.

  一种图像形成方法，其在记录介质的表面上应用预处理液，并在应用预处理液的表面上应用包括颜料、水溶性有机溶剂、表面活性剂和水的喷墨墨水，其中水溶性有机溶剂包括至少一种多元醇，其在23℃和80%相对湿度下的平衡含水量不少于30%（重量百分比），具有以下式（I）的酰胺化合物，以及具有以下式（II）至（IV）之一的化合物，其中在100ms接触时间下，通过动态扫描液体吸收计测量，纯水向记录介质转移的量为1至15 mL/m2。
• RESIN COMPOSITION FOR STEREOLITHOGRAPHY
  申请人：Ito Takashi

  公开号：US20090209674A1

  公开（公告）日：2009-08-20

  Provided is a resin composition for stereolithography that absorbs little water and moisture over time in uncured state, maintains a low moisture absorption rate even under high humidity, and has high curing sensitivity, from which a stereolithography product excellent in the properties, such as dimensional accuracy, mechanical properties, and dimensional stability can be smoothly produced for reduced light irradiation time. The resin composition for stereolithography comprising an oxetane compound expressed by the general formula (I) below; (wherein R 1 denotes an alkyl group having 1 to 5 carbon atoms, and R 2 denotes an alkylene group having 2 to 10 carbon atoms that may contain an ether bond) in the proportion of from 3 to 60 mass % based on the total mass of the resin composition for stereolithography.

  提供了一种用于立体光刻的树脂组合物，其在未固化状态下吸收的水分和湿气很少，即使在高湿度下也保持低的吸湿率，并具有高的固化敏感性，可以顺利生产出具有尺寸精度、机械性能和尺寸稳定性等优良性能的立体光刻产品，从而减少光照时间。该立体光刻用树脂组合物包括以下通式(I)所表示的环氧乙烷化合物；（其中R1表示1至5个碳原子的烷基，R2表示含有2至10个碳原子的烷基，可能含有醚键），其比例为3至60质量％，基于立体光刻用树脂组合物的总质量。