4-phenoxy-N,N-bis(2-hydroxy-3-chloropropyl)aniline | 1246462-38-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-phenoxy-N,N-bis(2-hydroxy-3-chloropropyl)aniline
• 英文别名: 1-chloro-3-(N-(3-chloro-2-hydroxypropyl)-4-phenoxyanilino)propan-2-ol
• CAS: 1246462-38-3
• 化学式: C₁₈H₂₁Cl₂NO₃
• 分子量: 370.276
• InChiKey: OVZZXYZBKCKJIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-phenoxy-N,N-bis(2-hydroxy-3-chloropropyl)aniline 在 四丁基硫酸氢铵 、 sodium hydroxide 作用下， 以 水 、 甲苯 为溶剂， 反应 4.0h， 生成 4-phenoxy-N,N-diglycidyl aniline
  参考文献：
  名称：

  EPOXY COMPOUND AND MANUFACTURING METHOD THEREOF

  摘要：

  提供了一种由以下式表示的新型环氧化合物及其制备方法：其中R1和R2是从氢、具有1至4个碳原子的脂肪烃基、具有3至6个碳原子的脂环烃基、具有6至10个碳原子的芳香烃基、卤原子、醚基、酯基、酰基和硝基组成的群体中选择的成员，n是1至4的整数，m是1至5的整数。

  公开号：

  US20110040111A1
• 作为产物：
  描述：

  4-氨基二苯醚 、 环氧氯丙烷 在 氮 作用下， 以 乙醇 为溶剂， 反应 10.0h， 以to produce 4-phenoxy-N,N-bis(2-hydroxy-3-chloropropyl)aniline的产率得到4-phenoxy-N,N-bis(2-hydroxy-3-chloropropyl)aniline
  参考文献：
  名称：

  Epoxy compound and manufacturing method thereof

  摘要：

  提供了一种由以下公式表示的新型环氧化合物及其制备方法：其中，R1和R2是从氢、具有1至4个碳原子的脂肪烃基团、具有3至6个碳原子的脂环烃基团、具有6至10个碳原子的芳香烃基团、卤素原子、醚基、酯基、酰基和硝基组成的群体中选择的成员，n是1至4的整数，m是1至5的整数。

  公开号：

  US08415490B2

文献信息

• MANUFACTURING METHOD FOR COMPOUND HAVING N,N-BIS(2-HYROXY-3-CHLOROPROPYL)AMINO GROUP
  申请人：Toray Fine Chemicals Co., Ltd.

  公开号：US20180030013A1

  公开（公告）日：2018-02-01

  A method efficiently and safely manufactures, on an industrial scale, a compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group. (1) an amine compound or a solution thereof, (2) epichlorohydrin or a solution thereof, and (3) an acidic compound or a solution thereof are continuously supplied to a flow reactor and reacted at a reaction temperature of 40 to 130° C. and a liquid space velocity of 0.2 to 10 h −1 so that a compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group is manufactured. The obtained compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group is dehydrochlorinated by reaction with an alkali so that a polyfunctional glycidylamine type epoxy compound is manufactured.

  一种高效且安全地在工业规模上制造具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物的方法。将胺化合物或其溶液，环氧氯丙烷或其溶液，以及酸性化合物或其溶液连续供给到流动反应器中，在40至130°C的反应温度和0.2至10 h−1的液体空间速度下反应，从而制造出具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物。通过与碱反应将获得的具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物脱氯化，从而制造出一种多功能环氧化胺型环氧化合物。
• Epoxy resin composition for fiber-reinforced composite material, prepreg, and fiber-reinforced composite material
  申请人：Toray Industries, Inc.

  公开号：US08263216B2

  公开（公告）日：2012-09-11

  Disclosed is a fiber-reinforced composite material that is high in heat resistance and strength while being low in the content of volatile matter that volatilizes during curing. Also disclosed are an epoxy resin composition for production thereof, and a prepreg produced from the epoxy resin composition. Specifically the invention provides an epoxy resin composition comprising: [A] an epoxy resin comprising two or more ring structures each consisting of four or more members, and at least one amine type or ether type glycidyl group directly connected to the ring structures, [B] a tri- or more-functional epoxy resin, and [C] a curing agent, and also provides a prepreg produced by impregnating reinforcing fiber with the epoxy resin composition and a fiber-reinforced composite material produced by curing the prepreg.

  本发明公开了一种纤维增强复合材料，其热稳定性和强度高，同时挥发物含量低，不易在固化过程中挥发。还公开了用于生产该复合材料的环氧树脂组合物和由环氧树脂组合物制备的预浸料。具体而言，本发明提供了一种环氧树脂组合物，包括：[A]一种环氧树脂，其中包括两个或两个以上的环结构，每个环结构由四个或四个以上的成员组成，并且至少有一个胺型或醚型环氧基直接连接到环结构上，[B]一种三或多官能团的环氧树脂，以及[C]一种固化剂。本发明还提供了通过用环氧树脂组合物浸渍增强纤维制备的预浸料和通过固化预浸料制备的纤维增强复合材料。
• EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIALS, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20140309337A1

  公开（公告）日：2014-10-16

  Provided are: a fiber-reinforced composite material which is suppressed in morphology variation due to the molding conditions, while having excellent mode I interlaminar fracture toughness and excellent wet heat resistance; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements [A]-[F], and which is characterized by containing 5-25 parts by mass of constituent element [C] and 2-15 parts by mass of constituent element [E] per 100 parts by mass of the total epoxy resin blended therein. [A] A bifunctional amine type epoxy resin. [B] A tetrafunctional amine type epoxy resin. [C] A bisphenol F type epoxy resin having an epoxy equivalent weight of 450-4,500. [D] An aromatic amine curing agent. [E] A block copolymer having a reactive group that can be reacted with as epoxy resin. [F] Thermoplastic resin particles that are insoluble in an epoxy resin.

  提供了一种纤维增强复合材料，其在成型条件下具有抑制形态变化的特性，同时具有优异的I型层间断裂韧性和出色的耐湿热性能；一种用于制备纤维增强复合材料的环氧树脂组合物；以及使用该环氧树脂组合物制备的预浸料。一种用于纤维增强复合材料的环氧树脂组合物，其中至少包含以下组分[A]-[F]，并且其特征是每100份环氧树脂中含有5-25份组分[C]和2-15份组分[E]。[A] 双官能基胺型环氧树脂。[B] 四官能基胺型环氧树脂。[C] 具有450-4,500环氧当量重的双酚F型环氧树脂。[D] 芳香胺固化剂。[E] 具有可与环氧树脂反应的反应性基团的嵌段共聚物。[F] 在环氧树脂中不溶的热塑性树脂颗粒。
• PREPREG AND CARBON FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150210813A1

  公开（公告）日：2015-07-30

  A prepreg includes; sizing agent-coated carbon fibers coated with a sizing agent; and a thermosetting resin composition impregnated into the sizing agent-coated carbon fibers. The sizing agent includes an aliphatic epoxy compound (A) and an aromatic compound (B) at least containing an aromatic epoxy compound (B1). The thermosetting resin composition includes a thermosetting resin (D) and a latent hardener (E), and optionally includes an additive (F) other than the thermosetting resin (D) and the latent hardener (E). The (a)/(b) ratio is within a predetermined range where (a) is the height of a component at a binding energy assigned to CHx, C—C, and C═C and (b) is the height of a component at a binding energy assigned to C—O in a C 1s core spectrum of the surfaces of the sizing agent-coated carbon fibers analyzed by X-ray photoelectron spectroscopy.

  预浸料包括：涂有分散剂的碳纤维，涂有分散剂；以及浸渍在涂有分散剂的碳纤维中的热固性树脂组合物。分散剂包括脂肪族环氧化合物（A）和至少含有芳香族环氧化合物（B1）的芳香族化合物（B）。热固性树脂组合物包括热固性树脂（D）和潜在硬化剂（E），并且可选地包括除热固性树脂（D）和潜在硬化剂（E）以外的添加剂（F）。在由X射线光电子能谱分析的涂有分散剂的碳纤维表面的C1s光谱中，（a）是分配给CHx，C-C和C═C的结合能的组分高度，（b）是分配给C-O的结合能的组分高度，（a）/（b）比值在预定范围内。
• PREPREG AND CARBON FIBER REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150252184A1

  公开（公告）日：2015-09-10

  To provide a prepreg and a carbon fiber reinforced composite material that are excellent in adhesion between a matrix resin and carbon fibers and long-term storage stability and also excellent in microcrack resistance due to the increased toughness. The present invention provides a prepreg that includes; agent-coated carbon fibers coated with a sizing agent; and a thermosetting resin composition impregnated into the sizing agent-coated carbon fibers. The sizing agent includes an aliphatic epoxy compound (A) and an aromatic epoxy compound (B1). The sizing agent-coated carbon fibers are in a shape of woven fabric or braid. The thermosetting resin composition includes a thermosetting resin (D), a thermoplastic resin (F), and a latent hardener (G). The sizing agent-coated carbon fibers have an (a)/(b) ratio in a certain range where (a) is the height of a component at a binding energy assigned to CHx, C—C, and C═C and (b) is the height of a component at a binding energy assigned to C—O in a C 1s core spectrum of the surfaces of the sizing agent-coated carbon fibers analyzed by X-ray photoelectron spectroscopy.

  提供一种预浸料和碳纤维增强复合材料，其在基体树脂和碳纤维之间具有优异的附着性和长期储存稳定性，并且由于增加韧性而具有优异的微裂纹抗性。本发明提供一种预浸料，其包括：涂有分散剂的碳纤维；以及浸渍在涂有分散剂的碳纤维中的热固性树脂组合物。分散剂包括脂肪族环氧化合物（A）和芳香族环氧化合物（B1）。涂有分散剂的碳纤维呈编织物或编织带状。热固性树脂组合物包括热固性树脂（D）、热塑性树脂（F）和潜在硬化剂（G）。涂有分散剂的碳纤维在X射线光电子能谱分析的表面C1s谱中，具有（a）在分配给CHx、C—C和C═C的结合能处的组分高度和（b）在分配给C—O的结合能处的组分高度之间的（a）/（b）比率在一定范围内。