苯甲酰基氨基磷酸 | 36097-63-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯甲酰基氨基磷酸
• 英文名称: N-benzoylamidophosphoric acid
• 英文别名: dimethylbenzoylamidophosphate；N-benzoylphosphoramidic acid；benzoyl-amidophosphoric acid；Benzoyl-amidophosphorsaeure；N-Benzoyl-phosphamidsaeure；Phosphorsaeure-benzoylamid；N-benzoyl phosphoramidic acid；benzamidophosphonic acid
• CAS: 36097-63-9
• 化学式: C₇H₈NO₄P
• 分子量: 201.119
• InChiKey: QCWXBRLRXLWFJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.6
• 氢给体数：
  3
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  苯甲酰基氨基磷酸 生成
  参考文献：
  名称：

  磷酸酐与具有原性性质的有机化合物之间的相互作用

  摘要：

  摘要：磷酸酐已被证明与具有质子性质的有机化合物相互作用，即未取代和单取代的酰胺、嘧啶三酮、唑类和酯类。一些磷酸化产物倾向于表现出磷光性（1-3 和 1-4 位移）。

  DOI：

  10.1080/10426509608545191
• 作为产物：
  描述：

  N-4-benzoyl phosphoramidic dichloride 在 水 、 丙酮 作用下， 生成 苯甲酰基氨基磷酸
  参考文献：
  名称：

  Titherley; Worrall, Journal of the Chemical Society, 1909, vol. 95, p. 1151,1153

  摘要：

  DOI：

文献信息

• Coordination compounds based on CAPh type ligand: synthesis, structural characteristics and luminescence properties of tetrakis-complexes CsLnL₄ with dimethylbenzoylamidophosphate
  作者：Nataliia S. Kariaka、Victor A. Trush、Volodymyr V. Medviediev、Viktoriya V. Dyakonenko、Oleg V. Shishkin、Sergii S. Smola、Evgen M. Fadeyev、Nataliia V. Rusakova、Vladimir M. Amirkhanov

  DOI：10.1080/00958972.2015.1115024

  日期：2016.1.2

  Searching for prospective luminescent materials, the series of new lanthanide coordination compounds CsLnL(4) (Ln=La, Pr, Nd, Sm - Er, and Yb; L-=C6H5CONPO(OCH3)(2)}(-)) was synthesized. X-ray diffraction studies of CsNdL4 and CsYbL4 have been performed establishing polymeric structures of the tetrakis-complexes built from [LnL(4)](-) anions and cesium cations functioning as linkers. The IR, absorption, emission, excitation spectra, and decay time measurements at 298 and 77K, as well as thermal gravimetric analyses, were used to characterize the complexes.[GRAPHICS].
• Zavlin, P. M.; Efremov, D. A.; Tebby, J. C., Russian Journal of General Chemistry, 1994, vol. 64, # 8.1, p. 1175 - 1176
  作者：Zavlin, P. M.、Efremov, D. A.、Tebby, J. C.

  DOI：——

  日期：——
• Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements
  作者：Ramaswamy Murugavel、Mayank Pratap Singh

  DOI：10.1021/ic061298i

  日期：2006.11.1

  Copper(II) perchlorate and (PhCONH)P(O)(OH)(2) (H(2)bpa) react in methanol to yield [Cu(Hbpa)(2)](n), a novel layered solid that displays several interesting features. Unlike the previously reported copper phosphonates, a rare hexacoordination around the metal is observed in the title compound because of the amide C=O coordination to Cu in addition to the phosphoramidate P-O coordination. The six-membered chelate rings present in the title compound are made up of five different elements (Cu, P, C, N, and O).
• Sawlin P. M., Efremow D. A., Tebbi Dzh., Zh. obshh. khimii, 64 (1994) N 8, S 1308-1309
  作者：Sawlin P. M., Efremow D. A., Tebbi Dzh.

  DOI：——

  日期：——
• US4873355A
  申请人：——

  公开号：US4873355A

  公开（公告）日：1989-10-10