(Z)-3-(4-diphenylaminophenyl)-2-(4'-methylbiphenyl-4-yl)acrylonitrile | 1254816-54-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Z)-3-(4-diphenylaminophenyl)-2-(4'-methylbiphenyl-4-yl)acrylonitrile
• 英文别名: (Z)-2-[4-(4-methylphenyl)phenyl]-3-[4-(N-phenylanilino)phenyl]prop-2-enenitrile
• CAS: 1254816-54-0
• 化学式: C₃₄H₂₆N₂
• 分子量: 462.594
• InChiKey: VAVUQQVOPWEGMS-QFMPWRQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  27
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三苯胺 在 四(三苯基膦)钯 、 sodium methylate 、 sodium carbonate 、 三氯氧磷 作用下， 以 乙二醇二甲醚 、 乙醇 、 水 为溶剂， 反应 6.0h， 生成 (Z)-3-(4-diphenylaminophenyl)-2-(4'-methylbiphenyl-4-yl)acrylonitrile
  参考文献：
  名称：

  The synthesis and photoluminescence characteristics of novel α,β-diarylacrylonitrile derivatives containing both a biphenyl group and a triphenylamine unit

  摘要：

  2-(4-Bromophenyl)-3-(4-diphenylaminophenyl)acrylonitrile was prepared by the base catalysed condensation of 4-diphenylaminobenzaldehyde and 2-(4-bromophenyl)acetonitrile A series of alpha beta-dia-rylacrylonitrile derivatives containing both a biphenyl group and a triphenylamine unit were synthesized from 2-(4-bromophenyl)-3-(4-diphenylaminophenyl)acrylonitrile and boronic acids via a Suzuki reaction The structures of these compounds were characterized using FTIR H-1 NMR C-13 NMR MS and elemental analysis The UV-vis absorption and photoluminescent spectra of these derivatives were investigated These compounds emit green fluorescence with maximum emission peaks of 500-550 nm in CH2Cl2 solution and in the solid state under UV irradiation Analysis revealed good thermal stability with a decomposition temperature ranging from 279-386 degrees C (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.dyepig.2010.07.010

文献信息

• The synthesis and photoluminescence characteristics of novel α,β-diarylacrylonitrile derivatives containing both a biphenyl group and a triphenylamine unit
  作者：Bao Li、Qian Li、Bin Liu、Youfeng Yue、Mingxin Yu

  DOI：10.1016/j.dyepig.2010.07.010

  日期：2011.3

  2-(4-Bromophenyl)-3-(4-diphenylaminophenyl)acrylonitrile was prepared by the base catalysed condensation of 4-diphenylaminobenzaldehyde and 2-(4-bromophenyl)acetonitrile A series of alpha beta-dia-rylacrylonitrile derivatives containing both a biphenyl group and a triphenylamine unit were synthesized from 2-(4-bromophenyl)-3-(4-diphenylaminophenyl)acrylonitrile and boronic acids via a Suzuki reaction The structures of these compounds were characterized using FTIR H-1 NMR C-13 NMR MS and elemental analysis The UV-vis absorption and photoluminescent spectra of these derivatives were investigated These compounds emit green fluorescence with maximum emission peaks of 500-550 nm in CH2Cl2 solution and in the solid state under UV irradiation Analysis revealed good thermal stability with a decomposition temperature ranging from 279-386 degrees C (C) 2010 Elsevier Ltd All rights reserved