2-adamant-1-yl-2-methylbenzo[d][1,3]dithiole | 1425503-24-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-adamant-1-yl-2-methylbenzo[d][1,3]dithiole
• 英文别名: 2-(1-Adamantyl)-2-methyl-1,3-benzodithiole；2-(1-adamantyl)-2-methyl-1,3-benzodithiole
• CAS: 1425503-24-7
• 化学式: C₁₈H₂₂S₂
• 分子量: 302.505
• InChiKey: UYHCLPXSSOVHTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-adamant-1-yl-2-methylbenzo[d][1,3]dithiole 在 1,4-环己二烯 、 potassium tert-butylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以44%的产率得到1-乙基金刚烷
  参考文献：
  名称：

  Photoreduction of aliphatic and aromatic thioketals: new access to the reduction of carbonyl groups by a desulfurization chain process

  摘要：

  Aromatic and aliphatic ketones can be converted to methylene groups by desulfurization of the corresponding dithioketals in moderate to good yields. The reaction proceeds by photoinduced electron transfer from tert-BuOK in the presence of 1,4-dicyclohexadiene as hydrogen atom donor. The diene is able to trigger and keep a chain process by hydrogen transfer-proton transfer reactions. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.12.118

文献信息

• Photoreduction of aliphatic and aromatic thioketals: new access to the reduction of carbonyl groups by a desulfurization chain process
  作者：Gabriela Oksdath-Mansilla、Juan E. Argüello、Alicia B. Peñéñory

  DOI：10.1016/j.tetlet.2012.12.118

  日期：2013.3

  Aromatic and aliphatic ketones can be converted to methylene groups by desulfurization of the corresponding dithioketals in moderate to good yields. The reaction proceeds by photoinduced electron transfer from tert-BuOK in the presence of 1,4-dicyclohexadiene as hydrogen atom donor. The diene is able to trigger and keep a chain process by hydrogen transfer-proton transfer reactions. (c) 2013 Elsevier Ltd. All rights reserved.