(E)-octyl oct-2-enoate | 1350443-24-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-octyl oct-2-enoate
• 英文别名: octyl (E)-oct-2-enoate
• CAS: 1350443-24-1
• 化学式: C₁₆H₃₀O₂
• 分子量: 254.413
• InChiKey: YBKCEHARDSWALK-WYMLVPIESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  辛醇 、 2-辛烯酸 在 2C₃₃H₃₇N*H₂O₇S₂ 作用下， 以 水 为溶剂， 反应 19.0h， 以81%的产率得到(E)-octyl oct-2-enoate
  参考文献：
  名称：

  Hydrophobic N,N-Diarylammonium Pyrosulfates as Dehydrative Condensation Catalysts under Aqueous Conditions

  摘要：

  Oil-soluble N,N-diarylammonium pyrosulfates as nonsurfactant-type catalysts for the dehydrative ester condensation under aqueous conditions are described. Preheat treatment of dibasic sulfuric acid with bulky N,N-diarylamines generates water-tolerant salts of pyrosulfuric acid as active catalyst species. The present catalysts in water can also widely be applied to unusual selective esterifications and dehydrative glycosylation.

  DOI：

  10.1021/ol2027366

文献信息

• Hydrophobic <i>N,N-</i>Diarylammonium Pyrosulfates as Dehydrative Condensation Catalysts under Aqueous Conditions
  作者：Akira Sakakura、Yoshiki Koshikari、Matsujiro Akakura、Kazuaki Ishihara

  DOI：10.1021/ol2027366

  日期：2012.1.6

  Oil-soluble N,N-diarylammonium pyrosulfates as nonsurfactant-type catalysts for the dehydrative ester condensation under aqueous conditions are described. Preheat treatment of dibasic sulfuric acid with bulky N,N-diarylamines generates water-tolerant salts of pyrosulfuric acid as active catalyst species. The present catalysts in water can also widely be applied to unusual selective esterifications and dehydrative glycosylation.