4-Hexyl-5-phenyl-1-propyl-3-trimethylsilanyl-1,5-dihydro-pyrrol-2-one | 198214-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: 4-Hexyl-5-phenyl-1-propyl-3-trimethylsilanyl-1,5-dihydro-pyrrol-2-one
• 英文别名: 2H-Pyrrol-2-one, 4-hexyl-1,5-dihydro-5-phenyl-1-propyl-3-(trimethylsilyl)-；3-hexyl-2-phenyl-1-propyl-4-trimethylsilyl-2H-pyrrol-5-one
• CAS: 198214-13-0
• 化学式: C₂₂H₃₅NOSi
• 分子量: 357.611
• InChiKey: KWQWOVAIAXULPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.12
• 重原子数：
  25
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苯甲醛 、 alkaline earth salt of/the/ methylsulfuric acid 生成 4-Hexyl-5-phenyl-1-propyl-3-trimethylsilanyl-1,5-dihydro-pyrrol-2-one
  参考文献：
  名称：

  Synthesis of 1,5-dihydro-2H-pyrrol-2-ones from an alkyne, an imine and carbon dioxide via an organotitanium intermediate

  摘要：

  Azatitanacyclopentene complexes 2 react with carbon dioxide under atmospheric pressure to afford 1,5-dihydro-2H-pyrrol-2-ones, thus providing a one-pot procedure for synthesizing a variety of 1,5-dihydro-2H-pyrrol-2-ones from an alkyne, an imine and carbon dioxide under mild conditions. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01615-8

文献信息

• Synthesis of 1,5-dihydro-2H-pyrrol-2-ones from an alkyne, an imine and carbon dioxide via an organotitanium intermediate
  作者：Yuan Gao、Masaaki Shirai、Fumie Sato

  DOI：10.1016/s0040-4039(97)01615-8

  日期：1997.9

  Azatitanacyclopentene complexes 2 react with carbon dioxide under atmospheric pressure to afford 1,5-dihydro-2H-pyrrol-2-ones, thus providing a one-pot procedure for synthesizing a variety of 1,5-dihydro-2H-pyrrol-2-ones from an alkyne, an imine and carbon dioxide under mild conditions. (C) 1997 Elsevier Science Ltd.