4-hexylbenzene[2,3,4-tri(methoxy)benzal]imine | 257940-73-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-hexylbenzene[2,3,4-tri(methoxy)benzal]imine
• 英文别名: N-(4-hexylphenyl)-1-(2,3,4-trimethoxyphenyl)methanimine
• CAS: 257940-73-1
• 化学式: C₂₂H₂₉NO₃
• 分子量: 355.477
• InChiKey: ZGXLACWPBFGIEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  26
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  40
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (2-methylallyl)platinum chloride dimer 、 4-hexylbenzene[2,3,4-tri(methoxy)benzal]imine 以 甲醇 为溶剂， 以47%的产率得到di-μ-chlorobis[3,4,5-tris(methoxy)-2-([(4-hexylphenyl)imino]methyl)phenyl-C,N]diplatinum(II)
  参考文献：
  名称：

  A novel platinum methylene complex

  摘要：

  The dichlorobridged diplatinum organyls 4 and 5 undergo the expected chlorine-iodine exchange when treated with lithium iodide in diiodomethylene. Surprisingly, a second type of product, the triple-bridged (one methylene group plus two iodo units between the two Pt atoms) diplatinum complexes 7 and 8, respectively, are also formed in these unusual reactions. The formation of these latter two interesting, novel compounds takes place via a change of configuration of their two ligand sections from anti of their precursors (4 and 5, respectively) to syn present in 7 and 8; the mechanism of this process, however, is not yet clear. The molecular structures of 7 and 8 are based on an X-ray crystal analysis of 7 and on their comparable characteristic NMR data. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00441-6

文献信息

• A novel platinum methylene complex
  作者：Klaus Praefcke、Belkız Bilgin、Joachim Pickardt、Marina Borowski

  DOI：10.1016/s0022-328x(99)00441-6

  日期：1999.12

  The dichlorobridged diplatinum organyls 4 and 5 undergo the expected chlorine-iodine exchange when treated with lithium iodide in diiodomethylene. Surprisingly, a second type of product, the triple-bridged (one methylene group plus two iodo units between the two Pt atoms) diplatinum complexes 7 and 8, respectively, are also formed in these unusual reactions. The formation of these latter two interesting, novel compounds takes place via a change of configuration of their two ligand sections from anti of their precursors (4 and 5, respectively) to syn present in 7 and 8; the mechanism of this process, however, is not yet clear. The molecular structures of 7 and 8 are based on an X-ray crystal analysis of 7 and on their comparable characteristic NMR data. (C) 1999 Elsevier Science S.A. All rights reserved.