(4-chloro-2-methyl-phenoxy)-thioacetic acid | 22716-96-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (4-chloro-2-methyl-phenoxy)-thioacetic acid
• 英文别名: (4-Chlor-2-methyl-phenoxy)-thioessigsaeure；2-(4-chloro-2-methylphenoxy)ethanethioic S-acid
• CAS: 22716-96-7
• 化学式: C₉H₉ClO₂S
• 分子量: 216.688
• InChiKey: OELWFMFENYNUQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-甲基-4-氯苯氧乙酸 在 四氯化碳 、 sodium hydrogensulfide 、 五氯化磷 作用下， 生成 (4-chloro-2-methyl-phenoxy)-thioacetic acid
  参考文献：
  名称：

  Burstroem et al., Acta Agriculturae Scandinavica, 1956, vol. 6, p. 155,158

  摘要：

  DOI：

文献信息

• [EN] DENDRIMER AND FORMULATIONS THEREOF<br/>[FR] DENDRIMÈRE ET FORMULATIONS DE CEUX-CI
  申请人：STARPHARMA PTY LTD

  公开号：WO2017100856A1

  公开（公告）日：2017-06-22

  The present invention relates to a novel dendrimer. The present invention also relates to formulations comprising the dendrimer with improved characteristics. For instance, the present invention relates to formulations comprising pesticides such as 2- (2,4-dichlorophenoxy)acetic acid with improved characteristics such as reduced crystallisation, compatibility with hard water and an extended shelf life at low temperatures.

  本发明涉及一种新型树状聚合物。本发明还涉及含有具有改进特性的树状聚合物的配方。例如，本发明涉及含有农药（如2-(2,4-二氯苯氧)乙酸）的配方，其改进特性包括减少结晶、与硬水相容以及在低温下延长货架寿命。
• A new herbicidal composition, processes for its production and its use
  申请人：A. Nattermann & Cie. GmbH

  公开号：EP0068295A1

  公开（公告）日：1983-01-05

  The invention relates to new herbicidal compositions consisting of one or more herbicidally active substances and one or more certain phospholipides in addition to standard vehicles, diluents, solvents and/or other inert auxiliaries, the ratio by weight of the herbicidally active substance or mixture of herbicidally active substances to pure phospholipide or to the mixture of pure phospholipides amounting to between 1 : 0.2 and 1 : 20. The Invention also relates to processes for producing these compositions and to processes for controlling weeds and wild grasses using the new herbicidal compositions.

  本发明涉及新的除草组合物，除标准载体、稀释剂、溶剂和/或其它惰性助剂外，还包括一种或多种除草活性物质和一种或多种特定磷脂，除草活性物质或除草活性物质混合物与纯磷脂或纯磷脂混合物的重量比在 1 : 0.本发明还涉及生产这些组合物的工艺和使用新除草组合物控制杂草和野草的工艺。
• Use of membrane modulators and products comprising such membrane modulators
  申请人：A. Nattermann & Cie. GmbH

  公开号：EP0231765A1

  公开（公告）日：1987-08-12

  The invention is related to the use of certain water-soluble compounds known as such and having the Formula forthe modulation of membrane dependent metabolism processes within living cells, in particular with relation to transport phenomena and cell procedures which are induced or influenced by active agents supplied from outside the cell, products containing these substances for the above described uses and processes using these products.

  本发明涉及某些已知的水溶性化合物的用途，这些化合物具有调节活细胞内膜依赖性新陈代谢过程的配方，特别是与细胞外活性剂诱导或影响的运输现象和细胞程序有关的配方，以及含有这些物质的用于上述用途的产品和使用这些产品的工艺。
• N-[2-(pyridyl)propyl]-N-substituted sulfonamide, herbicide containing the same as an active ingredient and intermediate thereof
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0281110A2

  公开（公告）日：1988-09-07

  Disclosed herein is an N-[2-(pyridyl)propyl]-N-substituted sulfonamide represented by the following general ormula (I): wherein J represents a phenyl group which may be substituted or benzo-condensed, A represents -CH2-, -CH=CH-, -0-or -N(r)-(wherein r represents an alkyl group having 1 to 4 carbon atoms), b represents 0 or 1, R represents an alkyl group, alkenyl group, alkynyl group, alkoxy group, fluoroalkyl group or formyl group, D represents a hydroxyl group, E represents a halogen atom, an alkylsulfonyloxy group or a benzenesulfonyloxy group which may be substituted, or D and E represent -0-in combination, and V represents a pyridyl group which may be substituted, a herbicide containing said N-[2-(pyridyl)propyl]-N-substituted sulfonamide as an active ingredient and a 1-(halogenomethyl)vinylpyridine as an intermediate thereof.

  本发明公开了一种 N-[2-(吡啶基)丙基]-N-取代的磺酰胺，由以下通式(I)代表： 其中 J 代表可被取代或苯并缩合的苯基，A 代表-CH2-、-CH=CH-、-0-或-N(r)-(其中 r 代表具有 1 至 4 个碳原子的烷基)，b 代表 0 或 1，R 代表烷基、烯基、炔基、烷氧基、氟烷基或甲酰基，D 代表羟基、E 代表卤素原子、烷基磺酰氧基或可被取代的苯磺酰氧基，或 D 和 E 结合代表-0，V 代表可被取代的吡啶基，除草剂含有所述 N-[2-(吡啶基)丙基]-N-取代的磺酰胺作为活性成分和 1-(卤代甲基)乙烯基吡啶作为中间体。
• Indan-1,3-dione derivative and herbicidal composition containing the same as active ingredient
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0398258A1

  公开（公告）日：1990-11-22

  The present invention provides an indan-1,3-dione derivative represented by the following formula (I): wherein R¹ represents a hydrogen atom or a lower alkyl group; R² represents a group represented by wherein E represents a (substituted) phenyl group or a (substituted) pyridyl group; Y represents a hydroxyl group; and Z represents a halogen atom, a (substituted) alkylsulfonyloxy group or a (substituted) phenylsulfonyloxy group, or Y and Z are bonded to represent -O-; and A represents a (substituted) 1,3-butadienylene group or a (substituted) 1,3-­azabutadienylene group, and a herbicidal composition containing the same as an active ingredient. The present invention further provides an indan-1,3-dione derivative represented by the following formula (II): wherein R¹ and A represent the same meanings as above and R³ represents a group represented by wherein E represents the same meanings as above; and W¹ and W² each represents hydroxyl group or form a carbon-carbon bond by combining with each other, which is available as a synthetic intermediate for the compound of the formula (I). The compound of the formula (I) shows high herbicidal activity against gramineous weeds, cyperaceous weeds, etc. but shows markedly low phytotoxicity against crops.

  本发明提供了由下式(I)代表的茚-1,3-二酮衍生物： 其中 R¹代表氢原子或低级烷基； R²代表由以下式子表示的基团 其中E代表(取代的)苯基或(取代的)吡啶基；Y代表羟基；和Z代表卤素原子、(取代的)烷基磺酰氧基或(取代的)苯基磺酰氧基，或Y和Z键合代表-O-；和A代表(取代的)1，3-丁二烯基或(取代的)1，3-氮杂丁二烯基、 以及含有相同活性成分的除草组合物。 本发明进一步提供了由下式(II)代表的茚满-1,3-二酮衍生物： 其中 R¹ 和 A 代表与上述相同的含义，R³ 代表由下列式子表示的基团 其中 E 代表与上述相同的含义；W¹和 W² 各自代表羟基或通过相互结合形成碳-碳键，可作为式 (I) 化合物的合成中间体。 式（I）化合物对禾本科杂草、莎草科杂草等具有较高的除草活性，但对农作物的植物毒性明显较低。