bis-(6-chloro-hexyl)-disulfide | 854877-39-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: bis-(6-chloro-hexyl)-disulfide
• 英文别名: Bis-(6-chlor-hexyl)-disulfid；1-Chloro-6-(6-chlorohexyldisulfanyl)hexane
• CAS: 854877-39-7
• 化学式: C₁₂H₂₄Cl₂S₂
• 分子量: 303.361
• InChiKey: YBHCTWGZFPEMJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  16
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-甲基咪唑 、 bis-(6-chloro-hexyl)-disulfide 反应 48.0h， 生成 3,3'-[disulfanylbis(hexane-1,6-diyl)]bis(1-methyl-1H-imidazol-3-ium) dichloride
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation

  摘要：

  The synthesis and processing of nanoparticles consisting of metallic nanocrystal cores and organic monolayer shells promise interesting technological applications. Here, we report the synthesis of gold nanoparticles modified with ionic liquids based on the imidazolium cation. Aggregation-induced color changes of the gold nanoparticles in an aqueous solution were used as an optical sensor for anions via anion exchange of ionic liquid moiety. We also demonstrated the phase transfer of the gold nanoparticles from aqueous media to ionic liquid.

  DOI：

  10.1021/ja039895g
• 作为产物：
  描述：

  6,6'-二硫烷二基二(1-己醇) 在 氯化亚砜 作用下， 反应 24.0h， 生成 bis-(6-chloro-hexyl)-disulfide
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation

  摘要：

  The synthesis and processing of nanoparticles consisting of metallic nanocrystal cores and organic monolayer shells promise interesting technological applications. Here, we report the synthesis of gold nanoparticles modified with ionic liquids based on the imidazolium cation. Aggregation-induced color changes of the gold nanoparticles in an aqueous solution were used as an optical sensor for anions via anion exchange of ionic liquid moiety. We also demonstrated the phase transfer of the gold nanoparticles from aqueous media to ionic liquid.

  DOI：

  10.1021/ja039895g

文献信息

• Vogelsang et al., Justus Liebigs Annalen der Chemie, 1950, vol. 569, p. 183,192
  作者：Vogelsang et al.

  DOI：——

  日期：——
• US4399075A
  申请人：——

  公开号：US4399075A

  公开（公告）日：1983-08-16
• Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation
  作者：Hideaki Itoh、Kensuke Naka、Yoshiki Chujo

  DOI：10.1021/ja039895g

  日期：2004.3.1

  The synthesis and processing of nanoparticles consisting of metallic nanocrystal cores and organic monolayer shells promise interesting technological applications. Here, we report the synthesis of gold nanoparticles modified with ionic liquids based on the imidazolium cation. Aggregation-induced color changes of the gold nanoparticles in an aqueous solution were used as an optical sensor for anions via anion exchange of ionic liquid moiety. We also demonstrated the phase transfer of the gold nanoparticles from aqueous media to ionic liquid.