Di-n-pentyl-sulfoxylat | 3359-73-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Di-n-pentyl-sulfoxylat
• 英文别名: Diam oxysulfide；1-pentoxysulfanyloxypentane
• CAS: 3359-73-7
• 化学式: C₁₀H₂₂O₂S
• 分子量: 206.349
• InChiKey: JUICXVGMEVMVGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Di-n-pentyl-sulfoxylat 生成 Methylsulfinsaeure-n-pentylester
  参考文献：
  名称：

  WENSCHUH E.; FAHSL R., PHOSPH. AND SULFUR, 1979, 6, NO 1-2, 329

  摘要：

  DOI：
• 作为产物：
  描述：

  戊醇 在 二氯化硫 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 Di-n-pentyl-sulfoxylat
  参考文献：
  名称：

  Organic Esters of Bivalent Sulfur. III. Sulfoxylates

  摘要：

  DOI：

  10.1021/jo01019a046

文献信息

• Wenschuh,E. et al., Zeitschrift fur Chemie, 1978, vol. 18, p. 379 - 380
  作者：Wenschuh,E. et al.

  DOI：——

  日期：——
• Eine neue Synthese von Alkansulfinsäure-estern durch Reaktion von Sulfoxylsäure-estern mit Alkyljodiden
  作者：Eberhard WENSCHUH、Reinhard FAHSL、Renate HÖHNE

  DOI：10.1055/s-1976-24227

  日期：——
• CROSSLINKING AGENT, CROSSLINKING METHOD, METHOD OF CONTROLLING GENE EXPRESSION, AND METHOD OF EXAMINING GENE FUNCTION
  申请人：Furuta Toshiaki

  公开号：US20090023140A1

  公开（公告）日：2009-01-22

  The present invention provides a crosslinking agent which have photodegradable protective groups at two ends to crosslink double-stranded nucleic acid, a nucleic acid and a protein or a polypeptide, or proteins or polypeptides, in particular, double-stranded RNA; a method for crosslinking a double-stranded RNA or the like using the same; a method for regulating gene expression, which can control the expression of a target gene at an arbitrary timing and location; and a method for examining a gene function. According to the present invention, crosslinking between double-stranded nucleic acids between a nucleic acid and a protein or a polypeptide, or between proteins or polypeptides, in particular, between double-stranded RNA can be easily formed, and in addition, the crosslinking can also be easily removed, so that the expression of a target gene can be easily controlled at an arbitrary timing and location with high efficiency. Hence, as a result, function examination and/or identification of a gene that is expressed at a specific timing and location can be performed. In addition, the RNAi effect of a double-stranded RNA (siRNA) that cannot be easily inhibited by a conventional caged compound can be inhibited, and the expression of a target gene can be easily controlled at an arbitrary timing and location.
• US8084625B2
  申请人：——

  公开号：US8084625B2

  公开（公告）日：2011-12-27
• Organic Esters of Bivalent Sulfur. III. Sulfoxylates
  作者：Q. E. Thompson

  DOI：10.1021/jo01019a046

  日期：1965.8