3-(4-formylphenoxy)-2-hydroxypropyl methacrylate | 101927-31-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-(4-formylphenoxy)-2-hydroxypropyl methacrylate
• 英文别名: FPHPMA；3-(4-Formylphenoxy)-2-hydroxypropyl 2-methylprop-2-enoate；[3-(4-formylphenoxy)-2-hydroxypropyl] 2-methylprop-2-enoate
• CAS: 101927-31-5
• 化学式: C₁₄H₁₆O₅
• 分子量: 264.278
• InChiKey: NFTSOMSTHPHHET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基丙烯酸缩水甘油酯 、 对羟基苯甲醛 在 四甲基溴化铵 作用下， 以 乙醇 为溶剂， 反应 10.0h， 以60%的产率得到3-(4-formylphenoxy)-2-hydroxypropyl methacrylate
  参考文献：
  名称：

  Switching preorganization and thermoresponsive behavior of a water-soluble polymer via light-tunable hydrogen bonding

  摘要：

  我们报告了一种通用方法，这种方法可以通过光调氢键（H-bonding）"二聚化 "或 "聚合 "来切换水溶性聚合物的预组织和热粘合行为。为此，在 25 °C 的可见光照射下，通过 3-(4-甲酰基苯氧基)-2-羟基丙基甲基丙烯酸酯与 OEGMA 的 RAFT 共聚，并将醛基完全转化为目标肟基，合成了 2-羟基-3-(4-羟基亚氨基甲基)苯氧基丙基甲基丙烯酸酯与低聚(乙二醇)甲基丙烯酸酯（OEGMA）的明确共聚物。利用动态光散射和变温 1H NMR 研究了这些肟基团的光异构化和稳定性，以及肟构型对预组织和热致伸缩行为的影响。结果表明，E-肟的光异构化在 76% 的 Z 型形成时达到平衡。此外，E-肟的自约束 H 键 "二聚化 "导致胶束体积变小，滞后性可忽略不计，而 Z 型肟的可扩展 H 键 "聚合 "导致胶束体积变大，滞后性显著。

  DOI：

  10.1039/c3sm00020f

文献信息

• INK-JET RECORDING METHOD
  申请人：Tsubaki Yoshinori

  公开号：US20070120881A1

  公开（公告）日：2007-05-31

  An ink-jet recording method which enables recording of precise images by using a photo-curable ink and an ink-jet recording apparatus is disclosed, comprising ejecting an ink from a recording head to form ink dots on a recording medium, and exposing the recording medium to an actinic ray, wherein at least one of the timing of ejecting the ink and the rate of conveying recording medium is controlled so that the number of ink dots per unit length is greater in the sub-scanning direction than in the main scanning direction.

  本发明公开了一种喷墨记录方法和喷墨记录设备，利用光可固化墨水实现精确图像记录，包括从记录头喷出墨水以形成记录介质上的墨点，并将记录介质暴露于活性光线下。其中，控制至少一种喷墨墨水的喷出时机和记录介质传送速率，使单位长度上的墨点数在次扫描方向上大于主扫描方向上的墨点数。
• INK-JET INK AND INK-JET RECORDING METHOD
  申请人：TSUBAKI Yoshinori

  公开号：US20070115325A1

  公开（公告）日：2007-05-24

  An ink-jet is disclosed, comprising a colorant, water, a polymeric compound which is comprised of a hydrophilic backbone having plural side chains and is capable of curing via the side chains upon exposure to an actinic ray and a fluorine-containing surfactant having a specific structure. An ink-jet recording method is also disclosed.

  公开了一种喷墨，包括颜料、水、由具有多个侧链的亲水性骨架组成且能够通过侧链在接触到光致发生剂时固化的聚合物化合物和具有特定结构的含氟表面活性剂。还公开了一种喷墨记录方法。
• Ink-jet ink, ink-jet ink set and ink-jet recording method
  申请人：Ohkubo Kenichi

  公开号：US20070064050A1

  公开（公告）日：2007-03-22

  By employing an ink-jet ink and an ink-jet set characterized in that in an ink-jet ink incorporating at least water, an organic solvent, and a polymer compound having a plurality of side chains on a hydrophilic main chain, the polymer in which at least a part of the side chains are crosslinkable via exposure to actinic radiation, and the polymer exists in a dissolved state in the ink-jet ink, and the polymer has a property that all amount of the polymer is not dissolved in water when the polymer is mixed with water in an amount of the same content ratio as in the ink-jet ink, and an ink-jet recording method using the same, printing adaptability onto various printing media and ejection stability are achieved, and images exhibiting excellent color bleeding resistance and excellent beading resistance are prepared.

  通过使用一种喷墨墨水和一种喷墨墨水组合，其特征在于，所述喷墨墨水中至少包含水、有机溶剂和具有多个侧链的聚合物化合物，其主链具有亲水性。该聚合物至少部分的侧链可以通过暴露于光辐射而交联，并且该聚合物以溶解状态存在于喷墨墨水中。该聚合物具有一种特性，即当将聚合物与水以与喷墨墨水中相同的含量比例混合时，聚合物的全部量不会溶解于水中。使用此喷墨记录方法，可以实现适应各种印刷介质的印刷适应性和喷射稳定性，并制备出表现出优异的抗色渗透性和优异的抗珠状滴落性的图像。
• Ink-jet recording method
  申请人：Konica Minolta Holdings, Inc.

  公开号：US07588330B2

  公开（公告）日：2009-09-15

  An ink-jet recording method which enables recording of precise images by using a photo-curable ink and an ink-jet recording apparatus is disclosed, comprising ejecting an ink from a recording head to form ink dots on a recording medium, and exposing the recording medium to an actinic ray, wherein at least one of the timing of ejecting the ink and the rate of conveying recording medium is controlled so that the number of ink dots per unit length is greater in the sub-scanning direction than in the main scanning direction.

  本发明公开了一种利用光固化墨水和喷墨记录设备实现精确图像记录的喷墨记录方法，包括从记录头喷出墨水形成墨点到记录介质上，并将记录介质暴露于光线下。其中，至少控制墨水喷射时机或记录介质传送速率之一，以使单位长度内的墨点数在次扫描方向上大于主扫描方向上的墨点数。
• Method of ink-jet textile printing
  申请人：KONICA MINOLTA HOLDINGS, INC.

  公开号：EP1792955A1

  公开（公告）日：2007-06-06

  A method for ink-jet textile printing comprising the steps of: (a) ejecting a pigment ink from a recording head onto a fabric, wherein the pigment ink contains at least water, a pigment and a polymer, wherein the polymer has a plurality of side chains in a hydrophilic main chain and is capable of cross-linking between the side chains by irradiation of active energy rays, and (b) forming an image by irradiation of active energy rays onto the ink ejected areas.

  一种喷墨纺织品印花方法，包括以下步骤(a) 将颜料墨水从记录头喷射到织物上，其中颜料墨水至少包含水、颜料和聚合物，其中聚合物在亲水性主链中具有多个侧链，并能在活性能量射线的照射下在侧链之间交联；以及 (b) 通过在墨水喷射区域上照射活性能量射线形成图像。