1-amino-2,4,6-triphenylpyridinium perchlorate | 61777-42-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-amino-2,4,6-triphenylpyridinium perchlorate
• 英文别名: Pyridinium, 1-amino-2,4,6-triphenyl-, perchlorate；2,4,6-triphenylpyridin-1-ium-1-amine;perchlorate
• CAS: 61777-42-2
• 化学式: C₂₃H₁₉N₂*ClO₄
• 分子量: 422.868
• InChiKey: ADKSXEIOIGFCJJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.07
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-amino-2,4,6-triphenylpyridinium perchlorate 生成 2,4,6-三苯基吡啶
  参考文献：
  名称：

  MIKAELYAN, G. S.;AGBALYAN, S. G., XIMIYA GETEROTSIKL. SOED.,(1988) N 3, 424-425

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4,6-三苯基吡喃鎓高氯酸盐 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 4.0h， 生成 1-amino-2,4,6-triphenylpyridinium perchlorate
  参考文献：
  名称：

  On the Solution Chemistry of Parent Nitrenium Ion NH₂⁺:  The Role of the Singlet and Triplet States in Its Reactions with Water, Methanol, and Hydrocarbons

  摘要：

  Chemical reactions of the parent nitrenium ion NH2+ were examined. The latter was generated in various solutions through photolysis of 1-amino-2,4,6-triphenylpyridinium perchlorate. It was found that the hydrocarbons, toluene and triphenylmethane, trap NH2+ through two independent pathways. There is a free radical pathway which leads to bibenzyl (in the case of toluene) or the trityl radical (in the case of triphenylmethane). There is also a hydride transfer pathway which leads to benzyltoluene (in the case of toluene) or triphenylmethanol (in the case of triphenylmethane). Results from dilution, triplet sensitization, and EPR experiments lead to the assignment of the hydride transfer pathway to the singlet state of NH2+ and the radical pathway to the triplet state of NH2+. Trapping experiments with H2O and CH3OH were also carried out, and it was shown that the singlet state of NH2+ undergoes a net insertion into the O-H bonds of these substrates.

  DOI：

  10.1021/jo990324+
• 作为试剂：
  描述：

  甲苯 在 1-amino-2,4,6-triphenylpyridinium perchlorate 、 三氟乙酸 作用下， 生成 4-甲基二苯甲烷 、 苄基甲苯 、 1,2-二苯乙烷
  参考文献：
  名称：

  On the Solution Chemistry of Parent Nitrenium Ion NH₂⁺:  The Role of the Singlet and Triplet States in Its Reactions with Water, Methanol, and Hydrocarbons

  摘要：

  Chemical reactions of the parent nitrenium ion NH2+ were examined. The latter was generated in various solutions through photolysis of 1-amino-2,4,6-triphenylpyridinium perchlorate. It was found that the hydrocarbons, toluene and triphenylmethane, trap NH2+ through two independent pathways. There is a free radical pathway which leads to bibenzyl (in the case of toluene) or the trityl radical (in the case of triphenylmethane). There is also a hydride transfer pathway which leads to benzyltoluene (in the case of toluene) or triphenylmethanol (in the case of triphenylmethane). Results from dilution, triplet sensitization, and EPR experiments lead to the assignment of the hydride transfer pathway to the singlet state of NH2+ and the radical pathway to the triplet state of NH2+. Trapping experiments with H2O and CH3OH were also carried out, and it was shown that the singlet state of NH2+ undergoes a net insertion into the O-H bonds of these substrates.

  DOI：

  10.1021/jo990324+

文献信息

• Reactions of heterocyclic cations with N-containing nucleophiles. 13. Investigation of the reaction of 2,4,6-triarylpyrylium salts with hydrazines, semicarbazide, and thiosemicarbazide
  作者：�. A. Zvezdina、M. P. Zhdanova、O. S. Anisimova、G. N. Dorofeenko

  DOI：10.1007/bf00514471

  日期：1983.5
• Katritzky, Alan R.; Grzeskowiak, Nicholas E.; Alajarin-Ceron, Mateo, Journal of Chemical Research, Miniprint, 1982, # 8, p. 2164 - 2195
  作者：Katritzky, Alan R.、Grzeskowiak, Nicholas E.、Alajarin-Ceron, Mateo、Bahari, Zakaria bin、Beltrami, Hector A.、Keay, James G.

  DOI：——

  日期：——
• ZVEZDINA EH. A.; ZHDANOVA M. P.; DOROFEENKO G. N., XIMIYA GETEROTSIKL. SOEDIN., 1979, HO 3, 324-328
  作者：ZVEZDINA EH. A.、 ZHDANOVA M. P.、 DOROFEENKO G. N.

  DOI：——

  日期：——
• KATRITZKY, A. R.;GRZESKOWIAK, N. E.;ALAJARIN-CERON, M.;BAHARI, ZAKARIA, B+, J. CHEM. RES. MICROFICHE, 1982, N 8, 208-209
  作者：KATRITZKY, A. R.、GRZESKOWIAK, N. E.、ALAJARIN-CERON, M.、BAHARI, ZAKARIA, B+

  DOI：——

  日期：——
• ZVEZDINA, EH. A.;ZHDANOVA, M. P.;ANISIMOVA, O. S.;DOROFEENKO, G. N., XIMIYA GETEROTSIKL. SOEDIN., 1983, N 5, 695-701
  作者：ZVEZDINA, EH. A.、ZHDANOVA, M. P.、ANISIMOVA, O. S.、DOROFEENKO, G. N.

  DOI：——

  日期：——