N-o-chlorophenylphenylacetamidine | 37829-00-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-o-chlorophenylphenylacetamidine
• 英文别名: N-(2-chloro-phenyl)-2-phenyl-acetamidine；N-(2-Chlor-phenyl)-2-phenyl-acetamidin；C-Phenyl-N-(2-chlor-phenyl)-acetamidin；N'-(2-chlorophenyl)-2-phenylethanimidamide
• CAS: 37829-00-8
• 化学式: C₁₄H₁₃ClN₂
• 分子量: 244.724
• InChiKey: WPHPQSRMLRWCLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  38.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-o-chlorophenylphenylacetamidine 在 N-氯代丁二酰亚胺 作用下， 以 氯仿 为溶剂， 反应 7.0h， 生成 [3-Benzyl-2-(2-chloro-phenyl)-2H-[1,2,4]thiadiazol-(5E)-ylidene]-phenyl-amine
  参考文献：
  名称：

  One-Pot Synthesis of 2-Aryl-3-phenyl(benzyl)-5-phenylimino-Δ⁴-1,2,4-thiadiazolines usingN-Chlorosuccinimide

  摘要：

  DOI：

  10.1055/s-1985-31118
• 作为产物：
  描述：

  1-叠氮基-2-氯苯 、 苯乙腈 在 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 反应 0.08h， 以63%的产率得到N-o-chlorophenylphenylacetamidine
  参考文献：
  名称：

  Su; Li; Zhang, Journal of Chemical Research - Part S, 2001, # 1, p. 32 - 33

  摘要：

  DOI：

文献信息

• Syntheses of condensed imidazoles by lead tetraacetate oxidation of amidines
  作者：S. Chaudhury、A. Debroy、M. P. Mahajan

  DOI：10.1139/v82-167

  日期：1982.5.1

  2-Phenylbenzimidazoles, 2-benzylbenzimidazoles, 2-phenyl-1H-naphtho[1,2-d]imidazole, and 2-benzyl-1H-naphtho[1,2-d]-imidazole have been synthesized in excellent yields (77–98%) by lead tetraacetate oxidation of suitable N-arylbenzamidines, N-arylphenylacetamidines, N-α-naphthylbenzamidine, and N-α-naphthylphenylacetamidine respectively. The mechanism of nitrene insertion and intramolecular competitive nitrene insertion leading to these heterocycles has also been discussed.

  已合成2-苯基苯并咪唑、2-苄基苯并咪唑、2-苯基-1H-萘[1,2-d]咪唑和2-苄基-1H-萘[1,2-d]-咪唑，产率优良（77-98%），通过适当的N-芳基苯甲酰胺、N-芳基苯乙酰胺、N-α-萘基苯甲酰胺和N-α-萘基苯乙酰胺的铅四乙酸盐氧化合成。还讨论了氮化物插入和分子内竞争性氮化物插入导致这些杂环的机制。
• Effect of theory-based feature correlations on typicality judgments
  作者：Woo-Kyoung Ahn、Jessecae K. Marsh、Christian C. Luhmann、Kevin Lee

  DOI：10.3758/bf03195270

  日期：2002.1

  In the present study, we examine what types of feature correlations are salient in our conceptual representations. It was hypothesized that of all possible feature pairs, those that are explicitly recognized as correlated (i.e., explicit pairs) and affect typicality judgments are the ones that are more likely theory based than are those that are not explicitly recognized (i.e., implicit pairs). Real-world categories and their properties, taken from Malt and Smith (1984), were examined. We found that explicit pairs had a greater number of asymmetric dependency relations (i.e., one feature depends on the other feature, but not vice versa) and stronger dependency relations than did implicit pairs, which were statistically correlated in the environment but were not recognized as such. In addition, people more often provided specific relation labels for explicit pairs than for implicit pairs; these labels were most often causal relations. Finally, typicality judgments were more affected when explicit correlations were broken than when implicit correlations were broken. It is concluded that in natural categories, feature correlations that are explicitly represented and affect typicality judgments are the ones about which people have theories.
• ROBEV, S. K., DOKL. BOLG. AN, 41,(1988) N2, S. 69-72
  作者：ROBEV, S. K.

  DOI：——

  日期：——
• ROBEV, S. K.;TZANOVA, TZ. M.;DICHEVA, M. A., DOKL. BOLG. AN, 42,(1989) N2, S. 51-54
  作者：ROBEV, S. K.、TZANOVA, TZ. M.、DICHEVA, M. A.

  DOI：——

  日期：——
• CHAUDHURY, S.;DEBROY, A.;MAHAJAN, M. P., CAN. J. CHEM., 1982, 60, N 9, 1122-1126
  作者：CHAUDHURY, S.、DEBROY, A.、MAHAJAN, M. P.

  DOI：——

  日期：——