苯胺,3-(2,3-二氟苯氧基)- | 87098-13-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 苯胺,3-(2,3-二氟苯氧基)-
• 英文名称: manganese(II) maleate
• 英文别名: maleic acid ; manganese (II)-maleate；Maleinsaeure; Mangan(II)-maleinat；Manganese monomaleate；(Z)-but-2-enedioate;manganese(2+)
• CAS: 87098-13-3
• 化学式: C₄H₂O₄*Mn
• 分子量: 168.995
• InChiKey: PCDVXBKFEVKXMQ-ODZAUARKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.96
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  水 、 苯胺,3-(2,3-二氟苯氧基)- 、 顺丁烯二酸 以 水 为溶剂， 生成 tetraaquabis(hydrogen maleato)manganese(II)
  参考文献：
  名称：

  Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study

  摘要：

  Transition-metal hydrogen maleates of composition M(C4H3O4)(2) center dot 4H(2)O, where M = Mn, Fe, Co, and Ni, and their solid solutions were synthesized and characterized by X-ray crystallography, IR spectroscopy, mass spectrometry, and thermal analysis. X-ray crystallography and IR spectroscopy showed that both intramolecular and intermolecular H-bonds exist in these compounds. The generation of continuous substitutional solid solutions with cation substitution in these compounds was studied. The thermolysis mechanism was studied for both transition-metal hydrogen maleates and their solid solutions. The composite produced by thermolysis is stable up to 1200 degrees C in flowing helium.

  DOI：

  10.1134/s0036023608090180
• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 sodium maleate 以 水 为溶剂， 生成 苯胺,3-(2,3-二氟苯氧基)-
  参考文献：
  名称：

  Transformation of maleato manganese(II): temperature effect and coordination modes

  摘要：

  Two maleato bipyridine manganese(11) coordination polymers [Mn(male)(bpy)(H2O)](n)(.)2nH(2)O (1) and [Mn(male)(bpy)](n) (2) (H-2 male = maleic acid, bpy = 2,2'-bipyridine) were prepared in an ice-bath and at room temperature respectively, and were spectroscopically and structurally characterized. Complex 1 obtained at low temperature, possesses a one-dimensional helical chain in the solid state with hepta-coordination number at the manganese center. At room temperature, the hydrated complex I was irreversibly converted into the thermodynamically stable dehydrated product 2 with octahedral coordination. A similar dehydration effect was observed for the maleato manganese(II) complex with a more conjugated phenanthroline (phen) ligand. The maleato manganese(II) coordination polymer [Mn(male)(phen)](n) (.) nH(2)O (3) can be converted into the dehydrated product [Mn(male)(phen)](n) (4) upon heating, while the resultant product retains a similar pattern of coordination mode. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.01.005

文献信息

• Anionic vinyl/dicarboxylic acid polymers and uses thereof
  申请人：——

  公开号：US20020049291A1

  公开（公告）日：2002-04-25

  Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.

  本发明揭示了可生物降解的阴离子聚合物，其包括重复的聚合亚单位，优选由乙烯醋酸酯或乙烯醇和马来酸酐、顺式顺酐或反式顺酐等二羧酸单体组成。在合成聚合物时采用自由基聚合，然后水解以用醇基替换酯基。聚合物可以与离子复合并/或与肥料或种子混合，以产生农业上有用的组合物。本发明的优选产品可以叶面施用、施于种子、肥料或施于生长植物相邻的土壤，以增强植物对养分的吸收。
• Fechtel, Guenter, Zeitschrift fur Chemie, 1989, vol. 29, # 1, p. 28
  作者：Fechtel, Guenter

  DOI：——

  日期：——
• Transformation of maleato manganese(II): temperature effect and coordination modes
  作者：Hong-Bin Chen、Hui Zhang、Jin-Mei Yang、Zhao-Hui Zhou

  DOI：10.1016/j.poly.2004.01.005

  日期：2004.3

  Two maleato bipyridine manganese(11) coordination polymers [Mn(male)(bpy)(H2O)](n)(.)2nH(2)O (1) and [Mn(male)(bpy)](n) (2) (H-2 male = maleic acid, bpy = 2,2'-bipyridine) were prepared in an ice-bath and at room temperature respectively, and were spectroscopically and structurally characterized. Complex 1 obtained at low temperature, possesses a one-dimensional helical chain in the solid state with hepta-coordination number at the manganese center. At room temperature, the hydrated complex I was irreversibly converted into the thermodynamically stable dehydrated product 2 with octahedral coordination. A similar dehydration effect was observed for the maleato manganese(II) complex with a more conjugated phenanthroline (phen) ligand. The maleato manganese(II) coordination polymer [Mn(male)(phen)](n) (.) nH(2)O (3) can be converted into the dehydrated product [Mn(male)(phen)](n) (4) upon heating, while the resultant product retains a similar pattern of coordination mode. (C) 2004 Elsevier Ltd. All rights reserved.
• Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study
  作者：L. I. Yudanova、V. A. Logvinenko、L. A. Sheludyakova、N. F. Yudanov、G. N. Chekhova、N. I. Alferova、V. I. Alekseev、P. P. Semyannikov、V. I. Lisoivan

  DOI：10.1134/s0036023608090180

  日期：2008.9

  Transition-metal hydrogen maleates of composition M(C4H3O4)(2) center dot 4H(2)O, where M = Mn, Fe, Co, and Ni, and their solid solutions were synthesized and characterized by X-ray crystallography, IR spectroscopy, mass spectrometry, and thermal analysis. X-ray crystallography and IR spectroscopy showed that both intramolecular and intermolecular H-bonds exist in these compounds. The generation of continuous substitutional solid solutions with cation substitution in these compounds was studied. The thermolysis mechanism was studied for both transition-metal hydrogen maleates and their solid solutions. The composite produced by thermolysis is stable up to 1200 degrees C in flowing helium.