acrylic acid-(3-dibutylamino-propyl ester) | 6288-21-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acrylic acid-(3-dibutylamino-propyl ester)
• 英文别名: Acrylsaeure-(3-dibutylamino-propylester)；3-(Dibutylamino)propyl prop-2-enoate
• CAS: 6288-21-7
• 化学式: C₁₄H₂₇NO₂
• 分子量: 241.374
• InChiKey: SYRNSZXGMVNJOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-(二丁基氨基)-1-丙醇 、 丙烯酸甲酯（MA） 在 N-苯基-2-萘胺 、 aluminum isopropoxide 作用下， 生成 acrylic acid-(3-dibutylamino-propyl ester)
  参考文献：
  名称：

  Acrylic Esters of Amino Alcohols

  摘要：

  DOI：

  10.1021/ja01177a064

文献信息

• Ethylene copolymers as sorbers of metallic ions from solutions
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0340975A1

  公开（公告）日：1989-11-08

  A copolymer is prepared, by high pressure radical polymerisation, of, by wt, 40-95 % of ethylene, 5 -60 % of at least one aminoalkyl acrylate of the formula: where R, is H or methyl, R2 and R3 each are C1 -4. alkyl and n is 1, 2, 3 or 4, and optionally also up to 20 % of another copolymerizable monomer, the copolymer having a number average molecular weight of 5000 to 50,000. The copolymer is molded to pellets, beads, sheets, mats, cloth or cartridges and used as a filter to sorb metal ions, other than Fe or Co, from waste industrial aqueous solution containing metal ions, e.g. ions of Pd, Cr or U, the solution being adjusted to appropriate pH. The copolymer can be washed with water of different pH to recover the metal; or it can be burnt and the metal recovered from the ash.

  通过高压自由基聚合法制备一种共聚物，按重量百分比计，由 40-95% 的乙烯、5-60% 的至少一种式中的氨基烷基丙烯酸酯组成： 式中 R 为 H 或甲基，R2 和 R3 分别为 C1 -4. 烷基，n 为 1、2、3 或 4，还可选择加入不超过 20% 的另一种可共聚单体，共聚物的平均分子量为 5000 至 50000。 将共聚物模塑成颗粒、珠子、薄片、垫子、布或滤芯，用作过滤器，从含有金属离子（如钯、铬或铀离子）的工业废水溶液中吸附除铁或钴以外的金属离子，溶液的 pH 值应调节到适当的水平。共聚物可以用不同 pH 值的水清洗，以回收金属；也可以焚烧，从灰烬中回收金属。
• DIENE RUBBER COMPOSITION
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0849321A1

  公开（公告）日：1998-06-24

  A rubber composition comprising 100 parts by weight of a diene rubber ingredient containing an amino group-containing diene rubber, 10 to 120 parts by weight of silica, 0.1 to 15 parts by weight a vulcanizer and 0.1 to 15 parts by weight of a sulfenamide vulcanization accelerator. This rubber composition exhibits excellent heat build-up, tensile property and abrasion resistance, and is suitable for tires and others.

  一种橡胶组合物，由 100 份（按重量计）含氨基的二烯橡胶成分、10 至 120 份（按重量计）白炭黑、0.1 至 15 份（按重量计）硫化剂和 0.1 至 15 份（按重量计）磺酰胺硫化促进剂组成。 这种橡胶组合物具有优异的蓄热性、拉伸性和耐磨性，适用于轮胎和其他产品。
• DIENE RUBBER, PROCESS FOR PRODUCING THE RUBBER AND RUBBER COMPOSITION CONTAINING THE SAME
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0882738A1

  公开（公告）日：1998-12-09

  A diene rubber comprised of a conjugated diene homopolymer or a conjugated diene/aromatic vinyl copolymer; the homopolymer or copolymer having at least one end of its polymer chain a quaternary ammonium group to which four carbon atoms have been bound, and containing 0 to 60% of aromatic vinyl units; at least 10% of the bound conjugated diene units being a vinyl bond; and the homopolymer or copolymer further having a weight average molecular weight (Mw) of 100,000 to 2,000,000. This rubber exhibits well reduced heat build-up, which is an index of a well reduced rolling resistance, and having tensile strength and abrasion resistance.

  一种二烯橡胶，由共轭二烯均聚物或共轭二烯/芳香族乙烯基共聚物组成；均聚物或共聚物的聚合物链至少一端有一个与四个碳原子结合的季铵基团，并含有 0 至 60% 的芳香族乙烯基单元；结合的共轭二烯单元中至少有 10% 是乙烯基键；均聚物或共聚物的重量平均分子量（Mw）为 100,000 至 2,000,000 。这种橡胶能很好地减少热量积聚（这是很好地减少滚动阻力的指标），并具有拉伸强度和耐磨性。
• Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and the use thereof
  申请人：SOLENIS TECHNOLOGIES, L.P.

  公开号：US10975525B2

  公开（公告）日：2021-04-13

  Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C 1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a)+(b)+(c)+(d)+(e)+(f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i)+(ii)+(iii)+(iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and card board.

  细粒度阳离子水性聚合物分散体，可通过乙烯基不饱和单体在含有阳离子预聚物作为分散剂 的水性液体中进行乳液聚合而获得，其中阳离子预聚物是在至少一种聚合引发剂存在下，通过 (a) 至少一种含有至少一个季铵基的乙烯基不饱和单体（重量百分比为 15%至 45%）的聚合制备而成；(b) 至少一种任选取代的苯乙烯，重量百分比为 5-80%； (c) 至少一种 C 1-12 烷基（甲基）丙烯酸酯，重量百分比为 0-50%； (d) 至少一种含酸基的乙烯基不饱和单体，重量百分比为 0-10%； (e) 至少一种含胺基的乙烯基不饱和单体，重量百分比为 0-10%；(f) 0 至 20%（重量）的至少一种不同于(b)、(c)和(e)的非离子乙烯基不饱和单体，(a)+(b)+(c)+(d)+(e)+(f)的总和为 100%（重量）、在含有阳离子预聚物的水性液体中，在至少一种聚合引发剂的存在下，对单体混合物进行第二次乳液聚合，该单体混合物包括 (i) 10%至 70%（重量百分比）的任选取代的苯乙烯或（甲基）丙烯腈中的至少一种；(ii) 至少一种 CMS 烷基（甲基）丙烯酸酯（30%至 90%（重量比））； (iii) 至少一种线型或支链 C1-30 羧酸乙烯基酯（0%至 30%（重量比））；(iv) 0-30%（重量）的至少一种不同于(i)、(ii)和(iii)的非离子乙烯基不饱和单体，(i)+(ii)+(iii)+(iv)的总和为 100%（重量），第一乳液聚合和/或第二乳液聚合可选择在 0-10%（重量）的至少一种聚合调节剂存在下进行。根据本发明的聚合物分散体适合用作纸张、纸板和纸板的施胶剂。
• Rubber mixtures containing quaternary polymers and polar plasticizers
  申请人：——

  公开号：US20030220428A1

  公开（公告）日：2003-11-27

  The present invention relates to rubber mixtures containing at least one quaternary polymer and at least one polar synthetic plasticizer, to a process for their production and to their use in the production of rubber molded bodies.

  本发明涉及含有至少一种季化合物聚合物和至少一种极性合成增塑剂的橡胶混合物、其生产工艺以及在橡胶模塑体生产中的应用。