Δ⁵-Bicyclo<2.2.1>hepten-2,3-dicarbonsaeure-monoallylester | 5424-81-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Δ⁵-Bicyclo<2.2.1>hepten-2,3-dicarbonsaeure-monoallylester
• 英文别名: bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid monoallyl ester；3-[(Prop-2-en-1-yloxy)carbonyl]bicyclo[2.2.1]hept-5-ene-2-carboxylic acid；3-prop-2-enoxycarbonylbicyclo[2.2.1]hept-5-ene-2-carboxylic acid
• CAS: 5424-81-7
• 化学式: C₁₂H₁₄O₄
• 分子量: 222.241
• InChiKey: NAYPMICIEKVXEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Δ⁵-Bicyclo<2.2.1>hepten-2,3-dicarbonsaeure-monoallylester 、 (S)-(-)- α-甲基苄胺 在 氯化亚砜 、 三乙胺 作用下， 以 甲苯 为溶剂， 生成 、
  参考文献：
  名称：

  一种新的具有成本效益的双功能硫脲为有机小分子的高对映选择性醇解观-环状酸酐：增强的对映选择性的配置反转

  摘要：

  Abstractmagnified imageA novel inexpensive thiourea bifunctional organocatalyst which can promote the highly enantioselective (up to 95% ee) alcoholysis of meso‐cyclic anhydrides has been developed. Computational studies on the catalytic process as well as a synthetic application of this new catalyst are also presented.

  DOI：

  10.1002/adsc.200800761

文献信息

• ACTIVE ENERGY RAY-CURABLE INK COMPOSITION AND PRINTED MATTER
  申请人：DIC Corporation

  公开号：EP2258778A1

  公开（公告）日：2010-12-08

  Disclosed is an active energy ray-curable ink composition comprising a coloring agent, a binder resin, and a radically polymerizable varnish and/or a radically polymerizable monomer as main components. The coloring agent is a modified pigment wherein the surface of a pigment (A) is provided with a polymer (P) which is obtained by polymerizing a polymer (B), which is soluble in nonaqueous solvents, with at least one polymerizable unsaturated monomer (C), which is originally soluble in nonaqueous solvents but becomes insoluble or poorly soluble after polymerization. Also disclosed is a printed matter which has a coating film obtained by curing and drying the active energy ray-curable ink composition.

  本发明公开了一种活性能量射线固化油墨组合物，其主要成分包括着色剂、粘合剂树脂、可辐射聚合清漆和/或可辐射聚合单体。着色剂是一种改性颜料，其中颜料（A）的表面具有聚合物（P），聚合物（P）是通过将可溶于非水溶剂的聚合物（B）与至少一种可聚合的不饱和单体（C）聚合而得到的，不饱和单体（C）原本可溶于非水溶剂，但在聚合后变得不溶或溶解性很差。还公开了一种印刷品，其涂膜是通过固化和干燥活性能量射线固化油墨组合物获得的。
• US8399541B2
  申请人：——

  公开号：US8399541B2

  公开（公告）日：2013-03-19
• A Novel Cost-Effective Thiourea Bifunctional Organocatalyst for Highly Enantioselective Alcoholysis of<i>meso</i>-Cyclic Anhydrides: Enhanced Enantioselectivity by Configuration Inversion
  作者：Su-Xi Wang、Fen-Er Chen

  DOI：10.1002/adsc.200800761

  日期：2009.3

  Abstractmagnified imageA novel inexpensive thiourea bifunctional organocatalyst which can promote the highly enantioselective (up to 95% ee) alcoholysis of meso‐cyclic anhydrides has been developed. Computational studies on the catalytic process as well as a synthetic application of this new catalyst are also presented.