6-bromohex-5-en-1-ol | 919800-95-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 6-bromohex-5-en-1-ol
• 英文别名: 6-Bromohex-5-EN-1-OL
• CAS: 919800-95-6
• 化学式: C₆H₁₁BrO
• 分子量: 179.057
• InChiKey: YDQBEBCKWXMPEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5,6-dibromohexan-1-ol 在 氢氧化钾 作用下， 以 乙醚 为溶剂， 生成 6-bromohex-5-en-1-ol 、 5-bromohex-5-en-1-ol
  参考文献：
  名称：

  Synthesis of 2-methylidene-1-silacyclohexanes from 2,6-dibromohex-1-ene and polyhalosilanes

  摘要：

  Various 2-methylidene-l-silacyclohexanes were prepared by straightforward syntheses from readily available polychloro- or polyfluorosilanes, magnesium and 2,6-dibromohex-l-ene using Barbier-type conditions or a previously synthesized Grignard reagent. Good yields were obtained considering the low stability of the products in the reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.061

文献信息

• Synthesis of 2-methylidene-1-silacyclohexanes from 2,6-dibromohex-1-ene and polyhalosilanes
  作者：Silvia Díez-González、Luis Blanco

  DOI：10.1016/j.jorganchem.2006.08.061

  日期：2006.12

  Various 2-methylidene-l-silacyclohexanes were prepared by straightforward syntheses from readily available polychloro- or polyfluorosilanes, magnesium and 2,6-dibromohex-l-ene using Barbier-type conditions or a previously synthesized Grignard reagent. Good yields were obtained considering the low stability of the products in the reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.