(4S,6S,8S,10S)-10,11-epoxy-4,6,8-trimethoxy-1-undecene | 129952-29-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: (4S,6S,8S,10S)-10,11-epoxy-4,6,8-trimethoxy-1-undecene
• 英文别名: (2S)-2-[(2S,4S,6S)-2,4,6-trimethoxynon-8-enyl]oxirane
• CAS: 129952-29-0
• 化学式: C₁₄H₂₆O₄
• 分子量: 258.358
• InChiKey: VGUUIVPWXYNPLA-XUXIUFHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (4S,6S,8S,10S)-10,11-epoxy-4,6,8-trimethoxy-1-undecene 生成 (4S,6S,8S,10R)-4,6,8,10-tetramethoxypentadec-1-ene
  参考文献：
  名称：

  MORI, YUJI;KOHCHI, YASUNORI;OTA, TOSHIMI;SUZUKI, MAKOTO, TETRAHEDRON LETT., 31,(1990) N0, C. 2915-2916

  摘要：

  DOI：
• 作为产物：
  描述：

  (2S,4S,6S,8S)-1,2-O-isopropylidene-4,6,8-trimethoxy-10-undecene-1,2-diol 生成 (4S,6S,8S,10S)-10,11-epoxy-4,6,8-trimethoxy-1-undecene
  参考文献：
  名称：

  1,3-多元醇的合成研究。从蓝绿藻全合成（4S，6S，8S，10S，12R，14R，16R，18R，20R）九甲氧基-1-戊二烯

  摘要：

  已经合成了从某些蓝绿藻中分离的等规九壬基-1-戊二十碳烯，并确定了其绝对构型。

  DOI：

  10.1016/0040-4039(90)80183-m

文献信息

• Synthesis and absolute configuration of an isotactic nonamethoxy-1-pentacosene from the blue-green alga Scytonema ocellatum
  作者：Yuji Mori、Narumi Kawajiri、Hiroshi Furukawa、Richard E. Moore

  DOI：10.1016/s0040-4020(01)89416-3

  日期：1994.1

  Synthesis of the novel isotactic nonamethoy-1-pentacosene (3) isolated from the terrestrial blue-green alga Scytonema ocellatum was accomplished in a stereocontrolled manner and the absolute configuration was established.

  从立体蓝藻Scytonema ocellatum分离的新型全同立构nonothoy-1-pentacosene（3）的合成以立体控制的方式进行，并建立了绝对构型。
• Isotactic polymethoxy-1-alkenes from the terrestrial blue-green alga : Structure and synthesis
  作者：Yuji Mori、Yasunori Kohchi、Hirohide Noguchi、Makoto Suzuki、Shmuel Carmeli、Richard E. Moore、Gregory M.L. Patterson

  DOI：10.1016/s0040-4020(01)80955-8

  日期：1991.1

  Novel isotactic polymethoxy-1-alkenes – were isolated from the tolytoxin-producing blue-green alga . The gross structures and relative configurations were determined by NMR and mass spectral analysis. Synthesis of optically active – in a stereocontrolled manner established their absolute configurations.

  全同立构新颖polymethoxy-1-烯烃-是从tolytoxin生产蓝绿藻分离。通过NMR和质谱分析确定总体结构和相对构型。光学活性的合成-以立体控制的方式建立了它们的绝对配置。
• Isotactic polymethoxy 1-alkenes from blue-green algae. Synthesis and absolute stereochemistry
  作者：Yuji Mori、Yasunori Kohchi、Makoto Suzuki、Shmuel Carmeli、Richard E. Moore、Gregory M. L. Patterson

  DOI：10.1021/jo00002a027

  日期：1991.1

  Novel isotactic polymethoxy-1-alkenes 1-4 were isolated from tolytoxin-producing blue-green algae belonging to the family Scytonemataceae. Scytonema mirabile produced 1 and 2, whereas 3 and 4 were isolated from S. burmanicum. The gross structures and relative stereochemistries were determined by mass and NMR spectral analyses. The absolute configurations of 1-4 were established by direct comparison with optically active synthetic samples.
• MORI, YUJI;KOHCHI, YASUNORI;OTA, TOSHIMI;SUZUKI, MAKOTO, TETRAHEDRON LETT., 31,(1990) N0, C. 2915-2916
  作者：MORI, YUJI、KOHCHI, YASUNORI、OTA, TOSHIMI、SUZUKI, MAKOTO

  DOI：——

  日期：——
• MORI, YUJI;KOHCHI, YASUNORI;NOGUCHI, HIROHIDE;SUZUKI, MAKOTO;CARMELI, SHM+, TETRAHEDRON, 47,(1991) N7, C. 4889-4904
  作者：MORI, YUJI、KOHCHI, YASUNORI、NOGUCHI, HIROHIDE、SUZUKI, MAKOTO、CARMELI, SHM+

  DOI：——

  日期：——