3,5-Dodecadien-1-ol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3,5-Dodecadien-1-ol
• 英文别名: (3E,5E)-dodeca-3,5-dien-1-ol
• 化学式: C₁₂H₂₂O
• 分子量: 182.306
• InChiKey: QXDRQDKWTDCHOZ-XBLVEGMJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正辛醛 、 methyl 4-(dimethylphosphono)crotonate 生成 (3E, 5Z)-3,5-dodecadien-1-ol 、 3,5-Dodecadien-1-ol
  参考文献：
  名称：

  Synthesis and Characterization of the Four Geometrical Isomers of 3,5-Dodecadienyl Acetate.

  摘要：

  Practical convergent syntheses of the four geometrical isomers of 3,5-dodecadienyl acetate are presented. These substances have been characterized by NMR and mass spectroscopy. (3E,5Z)-3,5-Dodecadienyl acetate is the main female sex pheromone component of the leaf roller Bonagota cranaodes, which is an important insect pest in apples in South America.The isomeric 3,5-dodecadienyl acetates, as pure isomers and in defined mixtures, have been used as trap lures for Eying insects in field screening experiments in Lithuania. Although no insects were found in the control traps, the numbers of males caught in the baited traps were not high enough to be statistically significant.

  DOI：

  10.3891/acta.chem.scand.52-0930

文献信息

• Identification and synthesis of the sex pheromone of Phtheochroa cranaodes (Lepidoptera: Tortricidae)
  作者：C. Rikard Unelius、Alvaro Eiras、Peter Witzgall、Marie Bengtsson、Adelécio Kovaleski、Evaldo F. Vilela、Anna-Karin Borg-Karlson

  DOI：10.1016/0040-4039(96)00050-0

  日期：1996.2

  The pheromone of Phtheochroa cranaodes (Lepidoptera: Tortricidae) was identified as (3E,5Z)-3,5-dodecadienyl acetate (5) by GC-MS analysis of female gland extracts and field trapping of males with synthetic compound.

  通过雌性腺体提取物的GC-MS分析和雄性化合物与合成化合物的田间诱捕，将十字花科（鳞翅目：opter科）的信息素鉴定为（3 E，5 Z）-3,5-十二碳烯基乙酸酯（5）。
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：JNC CORPORATION

  公开号：US20150299576A1

  公开（公告）日：2015-10-22

  A liquid crystal composition is described, containing at least one compound selected from compounds of formula (1) and at least one compound selected from compounds of formula (2): wherein, for example, X is —OH or —COOH; Z 1 is methylene; Z 2 , Z 3 , Z 4 and Z 5 are a single bond; L is —CH═CH—CH═CH—; R 1 is straight alkyl; P 1 , P 2 and P 3 are a polymerizable group; ring A and ring B are 1,4-phenylene or naphthalene-2,6-diyl; and a, b, c and d are 0 or 1.
• US9624435B2
  申请人：——

  公开号：US9624435B2

  公开（公告）日：2017-04-18