phenanthrene-3-carboxamide | 5345-43-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: phenanthrene-3-carboxamide
• 英文别名: Phenanthren-3-carbamid；3-Phenanthrenecarboxamide
• CAS: 5345-43-7
• 化学式: C₁₅H₁₁NO
• 分子量: 221.258
• InChiKey: VJLPGQYJETUIQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-氰基菲 在 potassium carbonate 作用下， 生成 phenanthrene-3-carboxamide
  参考文献：
  名称：

  Werner; Kunz, Justus Liebigs Annalen der Chemie, 1902, vol. 321, p. 323

  摘要：

  DOI：

文献信息

• Ionic Liquids for Separation of Olefin-Paraffin Mixtures
  申请人：Dai Sheng

  公开号：US20110015461A1

  公开（公告）日：2011-01-20

  The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group —N—SO 2 —(CF 2 ) n CF 3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  该发明涉及一种离子液体，包括（i）含有银（I）离子的阳离子部分，该离子与来自有机酰胺、有机胺、烯烃和有机腈中选择的一个或多个中性配体形成的络合物，以及（ii）具有化学式的阴离子部分，其中m和n独立地为0或大于1的整数，p为0或1，但当p为0时，由p支撑的基团—N—SO2—(CF2)nCF3将被连接到所示硫原子的氧原子替代。该发明还涉及一种从烯烃烷烃混合物中分离烯烃的方法，通过将混合物经过上述离子液体的一层来实现。
• Synthesis of Phenanthrene Derivatives. II.¹ Benzoylphenanthrenes and Derivatives
  作者：W. E. Bachmann

  DOI：10.1021/ja01306a051

  日期：1935.3
• Semantic aspects of morphological processing: Transparency effects in Serbian
  作者：Laurie Beth Feldman、Dragana Barac-Cikoja、Aleksandar Kostić

  DOI：10.3758/bf03194964

  日期：2002.6

  We examined the contribution of semantics to morphological facilitation in the visual lexical decision task at two stimulus onset asynchronies (SOAs) with Serbian materials. Primes appeared in Roman or Cyrillic characters. Targets always were printed in Roman. When primes were presented at an SOA of 250 msec, decision latencies to verbal targets (e.g., VOLIM) showed greatest facilitation after inflectionally (e.g., VOLE) related primes, significantly less after semantically transparent derived primes (e.g., ZAVOLE), and less again after semantically opaque derived primes (e.g., PREVOLE). Latencies after semantically transparent and opaque derived target words did not differ at an SOA of 48 msec. Both were slower than after inflectionally related primes. Stated generally, effects of semantic transparency among derivationally related verb forms were evident at long SOAs, but not at short ones. Under alphabet-alternating conditions, magnitudes of facilitation were greater overall, but the pattern was similar. The outcome suggests that restricted processing time for the prime limits the contribution of semantics to morphological processing and calls into question accounts that posit a task-invariant semantic criterion for morphological decomposition within the lexicon.
• IONIC LIQUIDS FOR SEPARATION OF OLEFIN-PARAFFIN MIXTURES
  申请人：UT-Battelle, LLC

  公开号：US20130338389A1

  公开（公告）日：2013-12-19

  The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group —N—SO 2 —(CF 2 ) n CF 3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.
• US8535560B2
  申请人：——

  公开号：US8535560B2

  公开（公告）日：2013-09-17