deca-2,4,6,8-tetrayne-1,10-diol | 62516-45-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: deca-2,4,6,8-tetrayne-1,10-diol
• 英文别名: Deca-2,4,6,8-tetrain-1,10-diol；2,4,6,8-Decatetrayn-1,10-Diol
• CAS: 62516-45-4
• 化学式: C₁₀H₆O₂
• 分子量: 158.156
• InChiKey: FWEVNBOGNPWUBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  deca-2,4,6,8-tetrayne-1,10-diol 在 吡啶 、 氯化亚砜 、 乙醚 作用下， 生成 1,10-dichloro-deca-2,4,6,8-tetrayne
  参考文献：
  名称：

  Cook et al., Journal of the Chemical Society, 1952, p. 2883,2889

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4-pentadiyne-1-ol 生成 deca-2,4,6,8-tetrayne-1,10-diol
  参考文献：
  名称：

  Metal salts of polyacetylenic compounds and uses thereof

  摘要：

  水溶性聚乙烯烯基碱金属盐，由二元、四元和六元二醇的羧甲基脲单体和聚合物，或相应的二酸制备而成；可用于热和辐射暴露指示剂和/或检测和/或去除溶解在水介质中的非碱金属离子。

  公开号：

  US04699997A1

文献信息

• Metal salts of polyacetylenic compounds and uses thereof
  申请人：Allied Corporation

  公开号：US04699997A1

  公开（公告）日：1987-10-13

  Water-soluble polyacetylenic alkali metal salts from monomers and polymers of carboxymethyl urethanes of di-, tetra-, and hexayne diols, or from the corresponding diacids; useful in thermal and irradiation exposure indicators and/or in detection and/or removal of nonalkali metal ions dissolved in aqueous media.

  水溶性聚乙烯烯基碱金属盐，由二元、四元和六元二醇的羧甲基脲单体和聚合物，或相应的二酸制备而成；可用于热和辐射暴露指示剂和/或检测和/或去除溶解在水介质中的非碱金属离子。
• Chemical synthesis of polymeric nanomaterials and carbon nanomaterials
  申请人：Olesik V. Susan

  公开号：US20060223947A1

  公开（公告）日：2006-10-05

  A high yield method for chemically synthesizing low polydispersivity carbon microspheres, nanospheres, nanocrystals, nanotubes, or nanofibers comprising dispersing a self-polymerizing end-capped polyyne in a solvent; heating the dispersed self-polymerizing end-capped tetrayne to form a polymeric material selected from the group consisting of polymer microspheres, polymer nanospheres, polymer nanocrystals, polymer nanotubes, and polymer nanofibers; and pyrolyzing the polymeric material to form a carbon material selected from the group consisting of carbon microspheres, carbon nanospheres, carbon nanocrystals carbon nanotubes, and carbon nanofibers, wherein the polydispersivity is less than 2.

  一种高产率的化学合成低聚散碳微球、纳米球、纳米晶体、纳米管或纳米纤维的方法，包括将自聚合端盖聚炔分散在溶剂中；加热分散的自聚合端盖四炔以形成聚合物材料，所述聚合物材料选自聚合物微球、聚合物纳米球、聚合物纳米晶体、聚合物纳米管和聚合物纳米纤维之组；并热解聚合物材料以形成碳材料，所述碳材料选自碳微球、碳纳米球、碳纳米晶体、碳纳米管和碳纳米纤维之组，其中聚散度小于2。
• Method for the preparation of a coating comprising oligomeric alkynes
  申请人：ÉCOLE POLYTECHNIQUE FÉDÉRALE DE LAUSANNE (EPFL) EPFL-TTO

  公开号：US10787576B2

  公开（公告）日：2020-09-29

  The invention relates to a method for the preparation of a coating comprising at least one coating layer on a substrate, the method comprising the steps of a. providing monomers of the type R—(N)x-(L)m-(C═C)n-(L′)o-(N′)y—R′, wherein R is a head moiety, R′ is a tail moiety, (C≡C)n is an oligoyne moiety, L and L′ are linker moieties, N and N′ independently are branched or unbranched optionally substituted C1-C25 alkyl moieties optionally containing 1 to 5 heteroatoms, x, m, o, and y are independently 0 or 1, n is 4 to 12, and wherein the head moiety allows for an interaction with the surface of the substrate; b. bringing the monomers into contact with the substrate wherein the interaction of the head moieties of the monomers with the surface of the substrate induces at least a part of the monomers to align in a defined manner thereby forming a film on the surface and bringing the oligoyne moieties of the monomers into close contact with each other; c. inducing a reaction between oligoyne moieties by providing an external stimulus so as to at least partially cross-link the aligned monomers, thereby forming a coating layer on the substrate. The invention further relates to a coating obtainable according to the method of the invention, the use of a coating obtainable according to the method of the invention, a substrate comprising a coating obtainable according to the invention and the use of solid substrate. The invention further relates to a method for the synthesis of the monomers according to the invention.

  本发明涉及一种在基底上制备包含至少一个涂层的涂层的方法，该方法包括以下步骤 a.提供R-(N)x-(L)m-(C═C)n-(L′)o-(N′)y-R′类型的单体，其中R是头部分子，R′是尾部分子，(C≡C)n是低碳原子分子，L和L′是连接分子、N和N′独立地是支链或未支链的任选取代的C1-C25烷基，任选含有1至5个杂原子，x、m、o和y独立地是0或1，n是4至12，其中头部分子允许与基质表面相互作用；b.使单体与基底接触，其中单体的头部分子与基底表面的相互作用诱导至少一部分单体以确定的方式排列，从而在表面上形成薄膜，并使单体的低聚酰亚胺分子彼此紧密接触； c. 通过提供外部刺激，诱导低聚酰亚胺分子之间发生反应，使排列的单体至少部分交联，从而在基底上形成涂层。本发明进一步涉及根据本发明方法可获得的涂层、根据本发明方法可获得的涂层的使用、包含根据本发明可获得的涂层的基底以及固体基底的使用。本发明进一步涉及根据本发明合成单体的方法。
• Bohlmann, Chemische Berichte, 1951, vol. 84, p. 785,793
  作者：Bohlmann

  DOI：——

  日期：——
• METHOD FOR THE PREPARATION OF A COATING
  申请人：Ecole Polytechnique Fédérale de Lausanne (EPFL) EPFL-TTO

  公开号：EP3303482A1

  公开（公告）日：2018-04-11