(Z)-11,13-tetradecadienyl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-11,13-tetradecadienyl acetate
• 英文别名: (11Z)-11,13-tetradecadien-1-yl acetate；11Z,13-Tetradecadienyl acetate；[(11Z)-tetradeca-11,13-dienyl] acetate
• 化学式: C₁₆H₂₈O₂
• 分子量: 252.397
• InChiKey: FNGLZFYTQNKDJT-PLNGDYQASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (11Z)-14-chloro-11-tetradecenyl acetate 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以84.43 %的产率得到(Z)-11,13-tetradecadienyl acetate
  参考文献：
  名称：

  HALOALKENYL ALKOXYMETHYL ETHER COMPOUND AND A PROCESS FOR PREPARING A TERMINAL CONJUGATED ALKADIEN-1-YL ACETATE COMPOUND AND A TERMINAL CONJUGATED ALKADIEN-1-OL COMPOUND THEREFROM

  摘要：

  本发明涉及以下通式（1）的卤代烯基烷氧甲基醚化合物：R1CH2OCH2OCH2CH2CH═CH(CH2)aX1（1），其中R1代表氢原子，具有1至9个碳原子的n-烷基或苯基，X1代表卤原子，“a”代表3至14的整数。本发明还涉及从卤代烯基烷氧甲基醚化合物（1）制备以下通式（5）的末端共轭烯丙二烯基乙酸酯化合物：CH2═CHCH═CH(CH2)aOAc（5），其中“a”如上定义，Ac代表乙酰基，以及以下通式（6）的末端共轭烯丙二烯基醇化合物：CH2═CHCH═CH(CH2)aOH（6），其中“a”如上定义。

  公开号：

  US20220106253A1

文献信息

• METHOD OF PRODUCING ALIPHATIC ALDEHYDE COMPOUND HAVING TERMINAL CONJUGATED DIENE STRUCTURE AND INTERMEDIATE THEREFOR
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20170297987A1

  公开（公告）日：2017-10-19

  Provided are a method for producing a terminal conjugated dienal compound without an oxidation reaction and a terminal hydroxyacetal compound useful as an intermediate in the method. More specifically, provided are a method for producing an (E)-dienal compound comprising the steps of: a metalation reaction of an alkynal acetal compound (1) to obtain an organic metal compound (2), an addition reaction of (2) to ethylene oxide to obtain a hydroxyalkynal acetal compound (3), a reduction reaction of (3) to obtain an (E)-hydroxyalkenal acetal compound (4), a functional group conversion reaction of (4) to obtain an (E)-alkenal acetal compound (5) having a leaving group X, an elimination reaction of (5) to obtain an (E)-dienal acetal compound (6), and a hydrolysis reaction of (6) to obtain the (E)-dienal compound (7); and others.

  提供了一种无需氧化反应的生产末端共轭二烯醛化合物和末端羟基缩醛化合物的方法。更具体地，提供了一种生产(E)-二烯醛化合物的方法，包括以下步骤：将炔醛缩醛化合物（1）进行金属化反应以得到有机金属化合物（2），将（2）加入到环氧乙烷中进行加成反应以得到羟基炔醛缩醛化合物（3），将（3）进行还原反应以得到(E)-羟基烯醛缩醛化合物（4），将（4）进行官能团转化反应以得到具有离去基X的(E)-烯醛缩醛化合物（5），将（5）进行消除反应以得到(E)-二烯醛缩醛化合物（6），最后进行水解反应以得到(E)-二烯醛化合物（7）；还包括其他步骤。
• Method of producing aliphatic aldehyde compound having terminal conjugated diene structure and intermediate therefor
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10040742B2

  公开（公告）日：2018-08-07

  Provided are a method for producing a terminal conjugated dienal compound without an oxidation reaction and a terminal hydroxyacetal compound useful as an intermediate in the method. More specifically, provided are a method for producing an (E)-dienal compound comprising the steps of: a metalation reaction of an alkynal acetal compound (1) to obtain an organic metal compound (2), an addition reaction of (2) to ethylene oxide to obtain a hydroxyalkynal acetal compound (3), a reduction reaction of (3) to obtain an (E)-hydroxyalkenal acetal compound (4), a functional group conversion reaction of (4) to obtain an (E)-alkenal acetal compound (5) having a leaving group X, an elimination reaction of (5) to obtain an (E)-dienal acetal compound (6), and a hydrolysis reaction of (6) to obtain the (E)-dienal compound (7); and others.

  本发明提供了一种无需氧化反应即可生产端基共轭二烯醛化合物的方法，以及一种可用作该方法中间体的端基羟基乙醛化合物。更具体地说，提供了一种生产(E)-二烯醛化合物的方法，该方法包括以下步骤：炔醛缩醛化合物 (1) 的金属化反应，得到有机金属化合物 (2)； (2) 与环氧乙烷的加成反应，得到羟基炔醛缩醛化合物 (3)； (3) 的还原反应，得到 (E)- 羟基烯醛缩醛化合物 (4)、(4)的官能团转化反应，得到具有离去基团 X 的(E)-烯醛缩醛化合物(5)；(5)的消去反应，得到(E)-二烯醛缩醛化合物(6)；(6)的水解反应，得到(E)-二烯醛化合物(7)；等。
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.