Benzoic acid (1S,3S,5R,6R,8R,10R)-5-hydroxy-8-methoxy-3-methyl-2,9-dioxa-tricyclo[4.3.1.0^3,8]dec-10-ylmethyl ester | 80454-52-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzoic acid (1S,3S,5R,6R,8R,10R)-5-hydroxy-8-methoxy-3-methyl-2,9-dioxa-tricyclo[4.3.1.0^3,8]dec-10-ylmethyl ester
• CAS: 80454-52-0
• 化学式: C₁₈H₂₂O₆
• 分子量: 334.369
• InChiKey: UEKRVKNGWBMHIR-MOGLDNESSA-N

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 Benzoic acid (1S,3S,5R,6R,8R,10R)-5-hydroxy-8-methoxy-3-methyl-2,9-dioxa-tricyclo[4.3.1.0^3,8]dec-10-ylmethyl ester 在 吡啶 作用下， 以33 mg的产率得到Benzoic acid (1S,3S,5R,6R,8R,10R)-5-acetoxy-8-methoxy-3-methyl-2,9-dioxa-tricyclo[4.3.1.0^3,8]dec-10-ylmethyl ester
  参考文献：
  名称：

  The structure of paeoniflorigenone, a new monoterpene isolated from paenoiae radix.

  摘要：

  A biologically active monoterpene, paeoniflorigenone (2), was isolated from the roots of Paeonia albiflora PALLAS. The structure of 2 was elucidated by means of chemical and spectral studies and its absolute structure was determined by X-ray analysis, by the direct method.

  DOI：

  10.1248/cpb.31.577
• 作为产物：
  描述：

  paeoniflorigenone 在 sodium tetrahydroborate 作用下， 以 乙醚 、 乙醇 、 二氯甲烷 为溶剂， 反应 1.0h， 生成 Benzoic acid (1S,3S,5R,6R,8R,10R)-5-hydroxy-8-methoxy-3-methyl-2,9-dioxa-tricyclo[4.3.1.0^3,8]dec-10-ylmethyl ester
  参考文献：
  名称：

  The structure of paeoniflorigenone, a new monoterpene isolated from paenoiae radix.

  摘要：

  A biologically active monoterpene, paeoniflorigenone (2), was isolated from the roots of Paeonia albiflora PALLAS. The structure of 2 was elucidated by means of chemical and spectral studies and its absolute structure was determined by X-ray analysis, by the direct method.

  DOI：

  10.1248/cpb.31.577