(3S,3aS,9S,9aS)-9-(tert-Butyl-dimethyl-silanyloxy)-3-[(R)-hydroxy-((2S,4S,5R)-5-hydroxy-2-methyl-[1,3]dioxan-4-yl)-methyl]-8-methoxy-3a,4,9,9a-tetrahydro-3H-naphtho[2,3-c]furan-1-one | 80631-95-4

• 分子结构分类: 有机化合物
• 英文名称: (3S,3aS,9S,9aS)-9-(tert-Butyl-dimethyl-silanyloxy)-3-[(R)-hydroxy-((2S,4S,5R)-5-hydroxy-2-methyl-[1,3]dioxan-4-yl)-methyl]-8-methoxy-3a,4,9,9a-tetrahydro-3H-naphtho[2,3-c]furan-1-one
• CAS: 80631-95-4
• 化学式: C₂₅H₃₈O₈Si
• 分子量: 494.657
• InChiKey: DMEYDXXEXKBOHA-YWYDNVBCSA-N

反应信息

• 作为产物：
  描述：

  (1R,2R,3S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-[(1S,2R)-1,2-diacetoxy-2-((2S,4S,5R)-5-acetoxy-2-methyl-[1,3]dioxan-4-yl)-ethyl]-8-methoxy-1,2,3,4-tetrahydro-naphthalene-2-carboxylic acid ethyl ester 在 potassium carbonate 作用下， 以 甲醇 为溶剂， 生成 (3S,3aS,9S,9aS)-9-(tert-Butyl-dimethyl-silanyloxy)-3-[(R)-hydroxy-((2S,4S,5R)-5-hydroxy-2-methyl-[1,3]dioxan-4-yl)-methyl]-8-methoxy-3a,4,9,9a-tetrahydro-3H-naphtho[2,3-c]furan-1-one
  参考文献：
  名称：

  Stereochemical control by an allylic substitutent of an acyclic dienophile in the Diels-Alder reaction

  摘要：

  DOI：

  10.1021/ja00368a038