Acetic acid (2S,3R,4R,5R,6S)-5-acetoxy-4-methoxy-6-methyl-2-[(6E,14E,16Z,18E)-4,16,22-triacetoxy-2-(2-acetoxy-1-methyl-butyl)-3,9,11,13,17,19,21-heptamethyl-8,20,24-trioxo-oxacyclotetracosa-6,14,16,18-tetraen-12-yloxy]-tetrahydro-pyran-3-yl ester | 135288-71-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酯类和类似物
• 英文名称: Acetic acid (2S,3R,4R,5R,6S)-5-acetoxy-4-methoxy-6-methyl-2-[(6E,14E,16Z,18E)-4,16,22-triacetoxy-2-(2-acetoxy-1-methyl-butyl)-3,9,11,13,17,19,21-heptamethyl-8,20,24-trioxo-oxacyclotetracosa-6,14,16,18-tetraen-12-yloxy]-tetrahydro-pyran-3-yl ester
• CAS: 135288-71-0
• 化学式: C₅₄H₈₀O₁₉
• 分子量: 1033.22
• InChiKey: GSSBYKJCXINENJ-PUFUBUKVSA-N

反应信息

• 作为产物：
  描述：

  乙酸酐 、 Maduralide 在 吡啶 作用下， 生成 Acetic acid (2S,3R,4R,5R,6S)-5-acetoxy-4-methoxy-6-methyl-2-[(6E,14E,16Z,18E)-4,16,22-triacetoxy-2-(2-acetoxy-1-methyl-butyl)-3,9,11,13,17,19,21-heptamethyl-8,20,24-trioxo-oxacyclotetracosa-6,14,16,18-tetraen-12-yloxy]-tetrahydro-pyran-3-yl ester
  参考文献：
  名称：

  Structure determination of maduralide: a new 24-membered ring macrolide glycoside produced by a marine bacterium (actinomycetales)

  摘要：

  Maduralide (1), a novel macrolide possessing a 24-membered ring, was isolated from a marine bacterium grown in liquid culture. The structure of this new metabolite was determined by spectroscopic methods.

  DOI：

  10.1016/s0040-4039(00)79914-x