摘要:
A new peroxo complex of Mo(VI), MoO(O2)2(Him)(H2O) (Him = imidazole), has been prepared from octamolybdate of imidazole, [H2im]4[Mo8O26(Him)2], and H2O2. The crystal and molecular structure was determined by X-ray crystallography and showed that the molybdenum atom is seven-coordinated with the nitrogen atom of the imidazole and the four oxygen atoms of the two peroxo groups in the equatorial plane while the oxygen atom and one water molecule occupy the apical positions of a pentagonal bipyramid.