| 178246-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 178246-51-0
• 化学式: C₂₈H₂₆N₄O₆
• 分子量: 514.538
• InChiKey: NITNCBWPVPCPES-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  氟硼酸钠 、 、 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical recognition of chloride ions by a poly [tris-(2,2′-bipyridine)ruthenium(II)] modified electrode

  摘要：

  The electrochemical behaviour of tris-substituted bipyridineruthenium(II) complexes containing a 4,4'-amide-disubstituted bipyridine ligand has been studied in the presence and the absence of halide anions. Voltammetric studies and UV-VIS spectrophotometric measurements confirm the selective binding ability of this redox-active receptor molecule towards Cl- among the halide anions. Platinum electrodes have been modified by electropolymerization of the parent pyrrole-substituted complex. A shift in potential of the first one-electron reduction of the redox-active polymer film in the presence of Cl- has been found. In contrast, no detectable influence of I- or Br- could be observed, while the electroactivity of the film is fully transformed in the presence of F-.

  DOI：

  10.1039/ft9969201527