| 139711-62-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• CAS: 139711-62-9
• 化学式: C₃₄H₃₄CdN₄O₅
• 分子量: 691.078
• InChiKey: KIIRGDBHGPDPTM-COBSGTNCSA-L

反应信息

• 作为反应物：
  描述：

  在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 以65%的产率得到10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a Methyl Ester
  参考文献：
  名称：

  A biomimetic partial synthesis of the red chlorophyll-a catabolite from Chlorella protothecoides.

  摘要：

  The red bilin derivative which is excreted in the culture medium by Chlorella protothecoides when this microalgae is grown in a medium rich in glucose but poor in nitrogen has been synthesized in two steps from one of the products of photo-oxidation of the Cd(II) complex of pyropheophorbide-a methyl ester. Under the same conditions, the Zn(II) complex of the latter is transformed into a blue bilin derivative which is an isomer of the foregoing chlorophyll-a catabolite.

  DOI：

  10.1016/s0040-4020(01)89871-9