azido[2,6-bis(2-benzimidazolyl-N(3))pyridine-N](methanol)(methanolato)nickel(II) | 164727-98-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: azido[2,6-bis(2-benzimidazolyl-N(3))pyridine-N](methanol)(methanolato)nickel(II)
• 英文别名: 2-[6-(1H-benzimidazol-2-yl)pyridin-2-yl]-1H-benzimidazole;methanol;methanolate;nickel(2+);azide
• CAS: 164727-98-4
• 化学式: C₂₁H₂₀N₈NiO₂
• 分子量: 475.132
• InChiKey: ILFIHLJVQZWQQA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium azide 、 [2,6-bis(2-benzimidazolyl)pyridine-N](Cl)2 nickel(II) *H2O 以 甲醇 为溶剂， 生成 azido[2,6-bis(2-benzimidazolyl-N(3))pyridine-N](methanol)(methanolato)nickel(II)
  参考文献：
  名称：

  Azido[2,6-bis(2-benzimidazolyl-N3)pyridine-N](methanol)(methanolato)nickel(II)

  摘要：

  The Ni-II atom in the title compound, [Ni(N-3)(CH3O)(CH4O)(C19H13N5)], is octahedrally coordinated by three N atoms from the tridentate 2,6-bis(2-benzimidazolyl)pyridine ligand, one N atom from the azide anion and two O atoms from methanol molecules. The four N atoms occupy equatorial positions of the octahedron, with Ni-N bond distances ranging from 2.O28(4) to 2.114(4) Angstrom. The methanol O atoms occupy axial positions with Ni-O bond distances of 2.074(3) and 2.151(3) Angstrom.

  DOI：

  10.1107/s0108270194011741