(16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) chloride | 186395-98-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: (16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) chloride
• CAS: 186395-98-2
• 化学式: C₂₀H₂₃N₄Pd*Cl
• 分子量: 461.302
• InChiKey: PAFBOYZMAGEETJ-GOBIVINZSA-M

反应信息

• 作为反应物：
  描述：

  (16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) chloride 在 NaOH 作用下， 以 甲醇 为溶剂， 以55%的产率得到(16-ethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II)
  参考文献：
  名称：

  Preparation and characterization of zinc(II) and palladium(II) complexes with 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo[b,i][1,4,8,11]-tetraazacyclotetradecine

  摘要：

  The zinc(II) and palladium(II) complexes of 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo [b,i][1,4,8,11] tetraazacyclotetradecine (HL(1)) and 5,14-dihydro-7,16-diethyldibenzo[b,i] [1,4,8,11]tetraazacyclotetradecine (H(2)L(2)) have been synthesized and their spectroscopic data determined. The absorption bands of ML(1)X (M = Zn,Pd; X = Cl, NCS, ClO4) observed in the 20,400-23,900 cm(-1) region were attributable to pi-pi* and charge transfer transitions. Those bands for the three palladium(II) complexes (PdL(1)X) are similar to each other in various solvents, but the bands of ZnL(1)X are slightly different from one another. The C-13 NMR signals for NiL(1)(ClO4) and PdL(1)(ClO4) are similar to each other, but the C(15) and C(17) carbon signals for ZnL(1)(ClO4) exhibit downfield shifts upon metal coordination. Judging from the molar conductances for the complexes, ZnL(1)(ClO4) and PdL(1)X (X = Cl, NCS, ClO4) are 1:1 electrolytes in acetonitrile and nitromethane, but ZnL(1)Cl and ZnL(1) (NCS) are non-electrolytes. The treatment of PdL(1)X (X=Cl, NCS, ClO4) in methanol solution with an excess of base in air gave (7-ethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) (PdL(3)). Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00342-7
• 作为产物：
  描述：

  ammonium chloride 、 palladium diacetate 、 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo<1,4,8,11>tetraazacyclotetradecine 以 甲醇 、 水 为溶剂， 以95%的产率得到(16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) chloride
  参考文献：
  名称：

  Preparation and characterization of zinc(II) and palladium(II) complexes with 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo[b,i][1,4,8,11]-tetraazacyclotetradecine

  摘要：

  The zinc(II) and palladium(II) complexes of 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo [b,i][1,4,8,11] tetraazacyclotetradecine (HL(1)) and 5,14-dihydro-7,16-diethyldibenzo[b,i] [1,4,8,11]tetraazacyclotetradecine (H(2)L(2)) have been synthesized and their spectroscopic data determined. The absorption bands of ML(1)X (M = Zn,Pd; X = Cl, NCS, ClO4) observed in the 20,400-23,900 cm(-1) region were attributable to pi-pi* and charge transfer transitions. Those bands for the three palladium(II) complexes (PdL(1)X) are similar to each other in various solvents, but the bands of ZnL(1)X are slightly different from one another. The C-13 NMR signals for NiL(1)(ClO4) and PdL(1)(ClO4) are similar to each other, but the C(15) and C(17) carbon signals for ZnL(1)(ClO4) exhibit downfield shifts upon metal coordination. Judging from the molar conductances for the complexes, ZnL(1)(ClO4) and PdL(1)X (X = Cl, NCS, ClO4) are 1:1 electrolytes in acetonitrile and nitromethane, but ZnL(1)Cl and ZnL(1) (NCS) are non-electrolytes. The treatment of PdL(1)X (X=Cl, NCS, ClO4) in methanol solution with an excess of base in air gave (7-ethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) (PdL(3)). Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00342-7