2-aminopyridinium malonate | 1393903-25-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-aminopyridinium malonate
• CAS: 1393903-25-7
• 化学式: C₃H₄O₄*C₅H₆N₂
• 分子量: 198.178
• InChiKey: XDSJVNOMIQCKKU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 丙二酸 以 水 为溶剂， 生成 2-aminopyridinium malonate
  参考文献：
  名称：

  Molecular interactions in 2-aminopyridinium malonate

  摘要：

  A new complex of 2-aminopyridine and malonic acid in a 1:1 stoichiometric ratio is obtained. The complex crystallizes in a centrosymmetric P2(1)/c space group with a = 3.8522(2), b = 17.5226(8), c = 13.7317(7) and beta = 94.418(3)A degrees. This complex is held by network of hydrogen bonds between the protonated 2-aminopyridinium cation and the malonate anion. There is no phase transition observed in this complex, which is verified using DSC and single crystal X-ray measurement studies. Unlike 2-aminopyridinium maleate, this complex crystallizes in the centrosymmetric space group and hence, this complex will not exhibit any non-linear optical property.

  DOI：

  10.1134/s0022476612020217