[Gd(III)(2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)))(picrate)3] | 460317-38-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Gd(III)(2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)))(picrate)3]
• 英文别名: [Gd(III)(2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)))(pic)3]
• CAS: 460317-38-8
• 化学式: C₄₂H₃₀GdN₁₁O₂₅
• 分子量: 1246.01
• InChiKey: MXEINARBGITTEO-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  gadolinium(III) picrate 、 2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)) 以 乙醇 为溶剂， 生成 [Gd(III)(2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)))(picrate)3]
  参考文献：
  名称：

  Complexation and extractability studies of lanthanide elements by 2,2′-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide))

  摘要：

  Solid complexes of lanthanide picrates with 2,2'-[1,2-phenylenebis(oxy)]-bis(N-methyl-N-phenyl(acetamide)) (L) have been prepared and characterized by elemental analysis, conductivity measurements, IR, electronic and H-1 NMR spectroscopies. The crystal structure of terbium complex shows a nona-coordination polyhedron in the form of a distorted mono-capped square antiprism. The extractability of lanthanide ions by L has been investigated using multitracer technology. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00329-2