[P(CH2NH2CH2C6H4F-4)(CH2N(CH2C6H4F-4)CH2N(CH2C6H4F-4)CH2]Cl | 1130652-00-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [P(CH2NH2CH2C6H4F-4)(CH2N(CH2C6H4F-4)CH2N(CH2C6H4F-4)CH2]Cl
• 英文别名: 4-FC6H4CH2NH2CH2P(cyclo-CH2N(CH2C6H4-4-F)CH2N(CH2C6H4-4-F)CH2))Cl
• CAS: 1130652-00-4
• 化学式: C₂₅H₂₇F₃N₃P*ClH
• 分子量: 493.939
• InChiKey: MZJZEGKXBHXDTH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 二氯甲烷 、 [P(CH2NH2CH2C6H4F-4)(CH2N(CH2C6H4F-4)CH2N(CH2C6H4F-4)CH2]Cl 以 二氯甲烷 为溶剂， 以93%的产率得到trans-[RhCl(CO)(P(CH2NH2CH2C6H4F-4)(CH2N(CH2C6H4F-4)CH2N(CH2C6H4F-4)CH2)2]Cl2*CH2Cl2
  参考文献：
  名称：

  Intramolecular Hydrogen-Bonded Tertiary Phosphines as 1,3,5-Triaza-7-phosphaadamantane (PTA) Analogues

  摘要：

  New cationic trialkylphosphines [P(CH2NH2R){CH2N(R)CH2N(R)CH2}](+) (R = C6H5CH2, a; 4-FC6H4CH2, b), as their Cl- (1a, 1b), SbF6- (2a, 2b), and PF6- (3a, 3b) salts, are described. The phosphine framework is conformationally locked, in the solid state, through pairs of intramolecular N-H center dot center dot center dot N hydrogen bonds which are maintained in the Ru-II and Rh-III complexes 4 and 5. Phosphines 1a-3b can be considered as charged variants of the well-known PTA ligand.

  DOI：

  10.1021/ic801709z