N-(3,5-Diazido-4-hydroxy-2,6-dimethyl-phenyl)-4-methyl-benzamide | 934415-88-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(3,5-Diazido-4-hydroxy-2,6-dimethyl-phenyl)-4-methyl-benzamide
• CAS: 934415-88-0
• 化学式: C₁₆H₁₅N₇O₂
• 分子量: 337.341
• InChiKey: XANFWISHPMBYIS-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  N-(3,5-Diazido-4-hydroxy-2,6-dimethyl-phenyl)-4-methyl-benzamide 在 lead(IV) acetate 作用下， 以 溶剂黄146 为溶剂， 以74%的产率得到N-(3,5-Diazido-2,6-dimethyl-4-oxo-cyclohexa-2,5-dienylidene)-4-methyl-benzamide
  参考文献：
  名称：

  Reaction of N-acyl-and N-[N-arylsulfonylbenz(acet)imidoyl]-1,4-benzoquinone monoimines with hydrazoic acid

  摘要：

  N-Aroyl-3,5-dimethyl- and N-[N-arylsulfonylbenz(acet)imidoyl]-3,5-dimethyl-1,4-benzoquinone monoimines react with hydrazoic acid according to the 1,4-addition pattern. N-Acyl-2,3,5,6-tetrachloro-1,4-benzoquinone monoimines take up hydrazoic acid at the double C=N bond (1,2-addition).

  DOI：

  10.1134/s1070428006060108
• 作为产物：
  描述：

  N-[3-Azido-2,6-dimethyl-4-oxo-cyclohexa-2,5-dien-(Z)-ylidene]-4-methyl-benzamide 在 sodium azide 作用下， 以 溶剂黄146 为溶剂， 反应 1.0h， 以82%的产率得到N-(3,5-Diazido-4-hydroxy-2,6-dimethyl-phenyl)-4-methyl-benzamide
  参考文献：
  名称：

  Reaction of N-acyl-and N-[N-arylsulfonylbenz(acet)imidoyl]-1,4-benzoquinone monoimines with hydrazoic acid

  摘要：

  N-Aroyl-3,5-dimethyl- and N-[N-arylsulfonylbenz(acet)imidoyl]-3,5-dimethyl-1,4-benzoquinone monoimines react with hydrazoic acid according to the 1,4-addition pattern. N-Acyl-2,3,5,6-tetrachloro-1,4-benzoquinone monoimines take up hydrazoic acid at the double C=N bond (1,2-addition).

  DOI：

  10.1134/s1070428006060108