Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin | 666237-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin
• CAS: 666237-31-6
• 化学式: C₁₁₈H₁₂₂N₈Zn₂
• 分子量: 1783.1
• InChiKey: WVRVXVHSPMXYCU-QZHYCZCKSA-N

反应信息

• 作为反应物：
  描述：

  Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin 在 sodium tetrachloroaurate(III) 作用下， 以 氯仿 为溶剂， 生成 Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin(1+)
  参考文献：
  名称：

  Triplet π-Diradical Dication of Directly meso−β-Linked Porphyrin Dimer

  摘要：

  Directly linked bisporphyrin, Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin, was investigated on the basis of the magnetic property of its bis(pi-radical cation). A stable triplet state of the bis(pi-radical cation) of the bisporphyrin, which obeys the Curie law, was successfully observed.

  DOI：

  10.1021/ja0385989