(O-Sn)-methanol-4-thioxo-3-thia-1,4a,9-triaza-fluorene-2-thiolate-triphenyltin | 1011469-15-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: (O-Sn)-methanol-4-thioxo-3-thia-1,4a,9-triaza-fluorene-2-thiolate-triphenyltin
• CAS: 1011469-15-0
• 化学式: C₂₈H₂₃N₃OS₃Sn
• 分子量: 636.386
• InChiKey: ZRJKHIUUMJFUGH-OLEWXMBDSA-M

反应信息

• 作为产物：
  描述：

  氘代甲醇 、 triphenyltin 4-thioxo-3-thia-1,4a,9-triaza-fluorene-2-thiolate 以 氘代甲醇 为溶剂， 生成 (O-Sn)-methanol-4-thioxo-3-thia-1,4a,9-triaza-fluorene-2-thiolate-triphenyltin
  参考文献：
  名称：

  Triphenyl lead, tin and germanium coordination compounds derived from 9H-3-thia-1,4a,9-triaza-fluorene-2,4-dithione

  摘要：

  Reactions of potassium 4-thioxo-3-tliia-1,4a,9-triaza-fluoretie-2-thiolate with Ph3PbCl, Ph3SnCl and Ph3GeCl provided the corresponding metal pentacoordinated compounds 2-4. Addition of THF afforded their hexacoordinated derivatives (5-7). Adducts of 2 and 3 with DMSO (8, 10), pyridine (9, 11), Ph3PO (12, 14) CH3OH (13, 15), respectively were synthesized. Compound 2 afforded the H2O adduct (16). In all cases the metal atom is chelated by the ligand through a covalent bond with S2 and a coordination bond with N1 forming four membered rings. Compounds were identified by H-1, C-13, N-15, Sn-119 and Pb-207. X-ray diffraction structures of 2, 3, 8, 9, 11, 14 and 16 were obtained. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.040