Na[2-P(2-OMe-Ph)2-4-Me-benzenesulfonate] | 1067229-38-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Na[2-P(2-OMe-Ph)2-4-Me-benzenesulfonate]
• CAS: 1067229-38-2
• 化学式: C₂₁H₂₀O₅PS*Na
• 分子量: 438.416
• InChiKey: ZEWFGJWUCGXCDC-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  trans-chloro(phenyl)bis(triphenylphosphine)nickel(II) 、 Na[2-P(2-OMe-Ph)2-4-Me-benzenesulfonate] 以 not given 为溶剂， 以87%的产率得到[NiPh(2-P(2-OMe-Ph)2-4-Me-benzenesulfonate)(triphenylphosphine)]
  参考文献：
  名称：

  Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes

  摘要：

  Base-free [2-PR2-4-Me-benzenesulfonate)]Ni(eta(3) -benzyl) complexes (R = 2-OMe-Ph (4a), Cy (4b)) were prepared and tested for ethylene polymerization. 4a produces low-molecular-weight polyethylene (M, = 1300) that contains 10 Me branches/10(3) C and terminal and internal olefin units. The polymer yield and structure are unaffected by the ethylene pressure (60-300 psi). 4b is less active than 4a and produces a polymer with higher M-n, fewer branches, and a higher fraction of terminal olefin units.

  DOI：

  10.1021/om800741w