| 1050537-19-3

• CAS: 1050537-19-3
• 化学式: C₁₈H₂₂Cl₃CrN₄O
• 分子量: 468.754
• InChiKey: XJVSQZZFMARLKX-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 1-[1-(3,5-Dimethylpyrazol-1-yl)-2-phenoxyethyl]-3,5-dimethylpyrazole 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  [NON]和[NSN]杂蝎配体的高选择性铬（III）乙烯三聚催化剂

  摘要：

  Cr(III) complexes with [NON] and [NSN] heteroscorpionate ligands derived from bis(pyrazol-1-yl)methane have been prepared, which are active for ethylene trimerization to 1-hexene with high selectivity. Structural studies have established the coordination of the ether or thioether pendant group, which leads to a bicyclic metallaheterocycle flanked by pyrazoyl rings.

  DOI：

  10.1021/om8005239