1-(2-methoxyphenyl)-3-thiophenyl-5-(benzthiazol-2-yl)formazane | 1268834-75-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 1-(2-methoxyphenyl)-3-thiophenyl-5-(benzthiazol-2-yl)formazane
• 英文别名: 1-(2-methoxyphenyl)-3-thiothenyl-5-(benzthiazol-2-yl)formazane
• CAS: 1268834-75-8
• 化学式: C₁₉H₁₅N₅OS₂
• 分子量: 393.493
• InChiKey: TUEFQESZCTYYMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.92
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  71.23
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  1-(2-methoxyphenyl)-3-thiophenyl-5-(benzthiazol-2-yl)formazane 、 nickel(II) acetate tetrahydrate 以 水 、 丙酮 为溶剂， 以57%的产率得到bis(1-(2-methoxyphenyl)-3-thiothenyl-5-(benzthiazol-2-yl)formazanato)nickel(II)
  参考文献：
  名称：

  Synthesis, characterization and ethylene oligomerization studies of nickel(II) based new formazane derivatives

  摘要：

  A series of nickel(II) complexes based novel mono- and bis-formazan ligands has been synthesized and characterized with IR, UV, NMR spectroscopies, CHN analysis, mass spectrometry, and single crystal X-ray diffraction analysis. The prepared complexes have been tested for catalytic activity in ethylene oligomerization. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.044
• 作为产物：
  描述：

  thiophene-2-carbaldehyde benzothiazol-2-yl-hydrazone 、 邻甲氧基苯胺 在 盐酸 、 sodium nitrite 作用下， 以 水 、 异丙醇 为溶剂， 以65%的产率得到1-(2-methoxyphenyl)-3-thiophenyl-5-(benzthiazol-2-yl)formazane
  参考文献：
  名称：

  Synthesis, characterization and ethylene oligomerization studies of nickel(II) based new formazane derivatives

  摘要：

  A series of nickel(II) complexes based novel mono- and bis-formazan ligands has been synthesized and characterized with IR, UV, NMR spectroscopies, CHN analysis, mass spectrometry, and single crystal X-ray diffraction analysis. The prepared complexes have been tested for catalytic activity in ethylene oligomerization. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.044

文献信息

• Synthesis, structure, and catalytic properties of iron complexes with mono- and bisformazans in sulfide oxidation and ethylene oligomerization reactions
  作者：I. S. Maksakova、I. G. Pervova、G. P. Belov、I. I. Khasbiullin、N. A. Ivanova、E. N. Frolova、I. N. Lipunov

  DOI：10.1134/s0965544115030068

  日期：2015.5

  numbers of iron atoms in a predominantly nitrogen-containing coordination environment have been synthesized on basis of benzothiazole mono- and bisformazans. The composition and structures of the resulting iron coordination compounds have been characterized by electronic absorption spectroscopy, elemental analysis, mass spectrometry, electron spin resonance, and magnetochemistry. The catalytic behavior

  在苯并噻唑单和双甲双氮的基础上，合成了主要在含氮配位环境中具有不同铁原子数的金属配合物。所得铁配位化合物的组成和结构已通过电子吸收光谱，元素分析，质谱，电子自旋共振和磁化学表征。研究了这些金属螯合物在硫化物的液相氧化和乙烯的低聚中的催化行为。