Diethyl N-(phosphonoacetyl)-2-naphthylamine | 153567-89-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Diethyl N-(phosphonoacetyl)-2-naphthylamine
• CAS: 153567-89-6
• 化学式: C₁₆H₂₀NO₄P
• 分子量: 321.313
• InChiKey: GINIVXZSDDOTPY-UHFFFAOYSA-N

物化性质

• 沸点：
  531.9±33.0 °C(predicted)
• 密度：
  1.238±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.04
• 重原子数：
  22.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  64.63
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  Diethyl N-(phosphonoacetyl)-2-naphthylamine 在 氢溴酸 作用下， 以 溶剂黄146 为溶剂， 以49%的产率得到(Naphthalen-2-ylcarbamoylmethyl)-phosphonic acid
  参考文献：
  名称：

  Plant-growth-regulatingN-(phosphonoacetyl)amines

  摘要：

  AbstractA series of N‐(phosphonacetyl)amine derivatives were synthesized and screened for plant‐growth regulating activity on Lepidium sativum L. and Cucumis sativus L. Aromatic N‐(phosphonoacetyl)amines. which may be considered as possible analogues of N‐acylaniline herbicides obtained by replacement of their acyl group by the phosphonacetyl moiety, exhibited significant or moderate herbicidal activity. In contrast, N‐(phosphonoacetyl)amino acids and N‐(phosphonoacetyl)aminophosphonic acids promoted the growth of L. sativum and C. sativus roots.

  DOI：

  10.1002/ps.2780400110
• 作为产物：
  描述：

  2-萘胺 、 alkaline earth salt of/the/ methylsulfuric acid 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 4.0h， 生成 Diethyl N-(phosphonoacetyl)-2-naphthylamine
  参考文献：
  名称：

  Plant-growth-regulatingN-(phosphonoacetyl)amines

  摘要：

  AbstractA series of N‐(phosphonacetyl)amine derivatives were synthesized and screened for plant‐growth regulating activity on Lepidium sativum L. and Cucumis sativus L. Aromatic N‐(phosphonoacetyl)amines. which may be considered as possible analogues of N‐acylaniline herbicides obtained by replacement of their acyl group by the phosphonacetyl moiety, exhibited significant or moderate herbicidal activity. In contrast, N‐(phosphonoacetyl)amino acids and N‐(phosphonoacetyl)aminophosphonic acids promoted the growth of L. sativum and C. sativus roots.

  DOI：

  10.1002/ps.2780400110