[Ag4(hfac)4(μ2-bpm)3] | 1005452-85-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Ag4(hfac)4(μ2-bpm)3]
• 英文别名: [Ag4(1,1,1,5,5,5-hexafluoroacetylacetonate)4(μ2-2,2'-bipyrimidine)3]
• CAS: 1005452-85-6
• 化学式: C₄₄H₂₂Ag₄F₂₄N₁₂O₈
• 分子量: 1734.17
• InChiKey: IJMVHQCKFCONRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ag4(hfac)4(THF)2].infin. 、 2 2'-联嘧啶 以 甲醇 为溶剂， 生成 [Ag4(hfac)4(μ2-bpm)3]
  参考文献：
  名称：

  Square-planar and trigonal prismatic silver(I) in bipyrimidine and oxalate bridged tetranuclear complexes and one-dimensional compounds: Synthesis and crystal structures

  摘要：

  The reaction of [Ag-4(hfac)(4)(THF)(2)] (hfac(-) = 1, 1, 1,5,5,5-hexafluoroacetylacetonate, THF = tetrahydrofurrane) with 2,2'-bipyrimidine (bpm) leads to single crystals. They crystallise in the triclinic system, space group P (1) over bar. Their structure consists of [Ag-4(hfac)(4)(mu(2)-bpm)(3)] tetranuclear complexes. In this complex, Ag(I) ions adopt distorted square planar and trigonal prismatic geometries. When [Ag-4(hfac)(4)(THF)(2)] is replaced by monohydrated silver(l) perchlorate, a one-dimensional (ID) compound with a formula of [[Ag(mu(2)-bpm)](n)(+), nClO(4)(-) is obtained as single crystals. They crystallise in the monoclinic system, space group P2(1)/c. Their structure consists of [[Ag(mu(2)-bpm)](+)](n), chains separated by non-coordinated perchlorate ions. In the chains, the Ag(I) centres adopt a square planar geometry. Finally, starting from [[Ag(mu(2)-bpm)](+)](n), nClO(4)(-) and sodium oxalate (Na(2)ox; ox = C2O42-), another 1D compound with a formula of [Ag(mu(2)-bpm)(mu(2)-ox)](n), 4nH(2)O is obtained as single crystals. They crystallise in the triclinic system, space group P (1) over bar. In these chains, bipyrimidine and oxalate are alternate. They generate a square planar geometry around the Ag(I) cations. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.06.023